Electrical Transport — Tuning Electrical- and Photo-Conductivity by Cation Exchange within a Redox-Active Tetrathiafulvalene-Based Metal–Organic Framework

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Me2NH2@1 pressed pellet · Pellet

Room temperature, ambient conditions, voltage swept from -1.5 V to 1.5 V; powder pressed at 10 tons; conductive carbon adhesive/gold wires.

Temperature: room temperature
Atmosphere: ambient
Geometry: Pressed pellet, two-probe
Context: Pristine parent framework control.
Measurement source: S3-S15 · Characterizations and conductivity discussion · Figure S12; Table S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical conductance replicate range	7.82e-12 to 7.86e-12 S	—	range	SI Table Range	S15 · Table S3 · Table S3
average room-temperature electrical conductivity	1.04x10-9 S cm-1	1.04e-7 S m-1	—	SI Table Exact Reported	S15 · Conductivity discussion · Table S3

MV@1 pressed pellet · Pellet

Room temperature, ambient conditions, voltage swept from -1.5 V to 1.5 V; powder pressed at 10 tons; conductive carbon adhesive/gold wires.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrical conductance replicate range	7.81e-10 to 7.92e-10 S	—	range	SI Table Range	S15 · Table S3 · Table S3
average room-temperature electrical conductivityMarked as a best value within this paper	1.32x10-7 S cm-1	0.0000132 S m-1	—	SI Table Exact Reported	S15 · Conductivity discussion · Table S3

TTF@1 pressed pellet · Pellet

Room temperature, ambient conditions, voltage swept from -1.5 V to 1.5 V; powder pressed at 10 tons; conductive carbon adhesive/gold wires.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
*conductivity enhancement after TTF+ or MV2+ exchange**	nearly two orders of magnitude; 10^2-fold	—	nearly	Text Approximate	18765 · Results and Discussion
electrical conductance replicate range	6.19e-10 to 6.41e-10 S	—	range	SI Table Range	S15 · Table S3 · Table S3
average room-temperature electrical conductivity	1.06x10-7 S cm-1	0.0000106 S m-1	—	SI Table Exact Reported	S15 · Conductivity discussion · Table S3