Measurement evidence
Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks · Benmansour S., Abherve A., Gomez-Claramunt P. et al. · ACS Applied Materials and Interfaces · 2017 · 26210-26218
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
compound 1 black shiny microcrystalline solid · Powder
Variable-temperature Q-band EPR spectra.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR signal appears at low temperature | ca. 20 K for compound 1 | — | — | Text Approximate | p005 · Magnetic Properties · Figure 6 |
compound 1 black shiny microcrystalline solid · Powder
Nexus-Nicolet 5700 spectrophotometer, 1800-400 cm-1 region in SI figure.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| IR nu(C=O) | 1626 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR nu(C-C) + nu(C-O) | 1355 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR nu(C=C) + nu(C-O) | 1482 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR delta(C-X) | 853 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR rho(C-X) | 573 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
compound 2 black shiny microcrystalline solid · Powder
Variable-temperature Q-band EPR spectra.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR signal appears at low temperature | ca. 40 K for compound 2 | — | — | Text Approximate | p005 · Magnetic Properties · Figure 6 |
compound 2 black shiny microcrystalline solid · Powder
Nexus-Nicolet 5700 spectrophotometer, 1800-400 cm-1 region in SI figure.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| IR nu(C=O) | 1624 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR nu(C-C) + nu(C-O) | 1353 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR nu(C=C) + nu(C-O) | 1482 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR delta(C-X) | 813 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |
| IR rho(C-X) | 554 cm-1 | — | — | SI Table Exact Reported | S-12 · Table S3 · Table S3 |