Other — Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks

4 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound 1 black shiny microcrystalline solid · Powder

DC susceptibility 2-300 K at 0.1 T; AC susceptibility 1.8-5 K, 0.395 mT, 1-1000 Hz; hysteresis at 1.8 K from -5 to 5 T.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature chi_m T	ca. 8.3 cm3 K mol-1	—	—	Text Approximate	p004 · Magnetic Properties · Figure 4
coercive field	ca. 1 mT	—	—	Text Approximate	p005 · Magnetic Properties · Figure S8
AC susceptibility ordering onset	nonzero out-of-phase signal below ca. 2.4 K	—	—	Text Approximate	p005 · Magnetic Properties · Figure 5

compound 1 black shiny microcrystalline solid · Powder

Thermogravimetric scan with progressive heating; atmosphere not specified.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
abrupt thermal decomposition temperature	ca. 350 C	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7
first TGA plateau mass loss	ca. 5.6% at ca. 130-140 C, corresponding to ca. 5 water molecules	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7
second-step cumulative TGA water loss	15.2% at ca. 190-200 C, corresponding to total ca. 13 water molecules	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7

compound 2 black shiny microcrystalline solid · Powder

DC susceptibility 2-300 K at 0.1 T; AC susceptibility 1.8-5 K, 0.395 mT, 1-1000 Hz; hysteresis at 1.8 K from -5 to 5 T.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature chi_m T	ca. 8.3 cm3 K mol-1	—	—	Text Approximate	p004 · Magnetic Properties · Figure 4
coercive field	ca. 1 mT	—	—	Text Approximate	p005 · Magnetic Properties · Figure S8
AC susceptibility ordering onset	nonzero out-of-phase signal below ca. 2.1 K	—	—	Text Approximate	p005 · Magnetic Properties · Figure 5

compound 2 black shiny microcrystalline solid · Powder

Thermogravimetric scan with progressive heating; atmosphere not specified.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
abrupt thermal decomposition temperature	ca. 310 C	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7
first TGA plateau mass loss	ca. 3.7% at ca. 130-140 C, corresponding to ca. 4 water molecules	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7
second-step cumulative TGA water loss	12.3% at ca. 190-200 C, corresponding to total ca. 12 water molecules	—	—	Text Approximate	S-6 · Thermogravimetric Analysis (TGA) · Figure S7