Microscopy Morphology — Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

compound 1 delaminated nanosheets on SiO2/Si · Nanosheet

AFM tapping mode on 300 nm SiO2/Si; TEM on TECNAI-F20 at 200 kV.

Geometry: drop-cast nanosheets on SiO2/Si
Context: pristine MOF nanosheets
Measurement source: S-8-S-9 · Characterization of the thin films · Figure 8; Figure S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tyndall effect after sonication	suspension showed Tyndall effect, confirming delamination	—	—	Qualitative Qualitative	S-8 · Delamination experiments · Figure S10
nanosheet bilayer count	ca. 7 bilayers	—	—	Calculated From Reported Approximate	p006 · Delamination as Nanosheets · Figure S11
nanosheet lateral dimensions	several micrometers	—	—	Text Qualitative	p006 · Delamination as Nanosheets · Figure 8
nanosheet thickness	ca. 7 nm	—	—	Text Approximate	p006 · Delamination as Nanosheets · Figure 8; Figure S11

compound 2 delaminated nanosheets on SiO2/Si · Nanosheet

AFM tapping mode on 300 nm SiO2/Si; TEM on TECNAI-F20 at 200 kV.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tyndall effect after sonication	suspension showed Tyndall effect, confirming delamination	—	—	Qualitative Qualitative	S-8 · Delamination experiments · Figure S10
nanosheet bilayer count	ca. 7 bilayers	—	—	Calculated From Reported Approximate	p006 · Delamination as Nanosheets · Figure S11
nanosheet lateral dimensions	several micrometers	—	—	Text Qualitative	p006 · Delamination as Nanosheets · Figure 8
nanosheet thickness	ca. 7 nm	—	—	Text Approximate	p006 · Delamination as Nanosheets · Figure 8; Figure S11