Spectroscopy — A Triptycene-Based 2D MOF with Vertically Extended Structure for Improving the Electrocatalytic Performance of CO2 to Methane

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

2D-vc-MOF(Cu) blue-black powder · Powder

EPR with sweep width 1500 G and centre field 3500 G.

Context: pristine target MOF
Measurement source: 3 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR semiquinone g value	g = 2.07	—	—	Text Exact Reported	3 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure S9

2D-vc-MOF(Cu) blue-black powder · Powder

Cu valence and local coordination analysis; EXAFS processed with Athena/Artemis.

Context: pristine target MOF
Measurement source: 2 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure 2b-c; Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu coordination number	coordination number is 4 for the Cu node	—	—	Text Exact Reported	2 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure 2c; Table S1
EXAFS fitted Cu-C distance	R = 2.68 +/- 0.15 A; CN = 4; sigma2 = 0.0178	—	+/-0.15 A	SI Table Exact Reported	24 · 4. Supporting Tables · Table S1
EXAFS fitted Cu-O distance	R = 1.92 +/- 0.07 A; CN = 4; sigma2 = 0.0051	—	+/-0.07 A	SI Table Exact Reported	24 · 4. Supporting Tables · Table S1
EXAFS Cu-O interaction distance, main-text peak	1.89 A	—	—	Text Exact Reported	2 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure 2c
Cu K-edge energy	8985 eV; close to CuO, Cu valency +2	—	—	Text Exact Reported	2 · The Synthesis and Characterization of 2D-vc-MOF(Cu) · Figure 2b

2D-vc-MOF(Cu) blue-black powder · Powder

Survey, high-resolution Cu 2p, C 1s, and O 1s spectra.

Context: pristine target MOF
Measurement source: 8-9, 24 · Supporting Figures and Tables · Figures S8-S10; Tables S2-S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu 2p1/2 XPS binding energy	954.5 eV, area 17.71%, FWHM 4.04	—	—	SI Table Exact Reported	24 · 4. Supporting Tables · Table S2
Cu 2p3/2 XPS binding energy	934.3 eV, area 42.17%, FWHM 3.89	—	—	SI Table Exact Reported	24 · 4. Supporting Tables · Table S2
O 1s C=O binding energy	531.5 eV, area 44.15%, FWHM 2.25	—	—	SI Table Exact Reported	24 · 4. Supporting Tables · Table S3
O 1s C-O binding energy	533.0 eV, area 55.85%, FWHM 2.56	—	—	SI Table Exact Reported	24 · 4. Supporting Tables · Table S3