Measurement evidence
Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks · Xie L.S., Alexandrov E.V., Skorupskii G. et al. · Chemical Science · 2019 · 8558-8565
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
As-synthesised bulk powder of compound 1 · Powder
MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR g value | 2.012 | — | — | Caption Exact Reported | S28 · EPR spectra · Fig. S15 |
As-synthesised bulk powder of compound 2 · Powder
MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR g value | 2.011 | — | — | Caption Exact Reported | S28 · EPR spectra · Fig. S15 |
As-synthesised bulk powder of compound 3 · Powder
MOF powders diluted 1 wt% with KBr and measured under nitrogen in septum-sealed quartz tubes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR g value | 2.012 | — | — | Caption Exact Reported | S28 · EPR spectra · Fig. S15 |
As-synthesised bulk powder of compound 1 · Powder
Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NIR IVCT band centre | approximately 4000 | — | — | Text Approximate | 8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| Optical band gap Eg from Tauc plot | 1.79 | — | — | Text Rounded Reported | 8563 · Diffuse reflectance spectroscopy · Fig. 7b |
| Higher-energy TTFTB radical-cation absorption band | approximately 21000 | — | — | Text Approximate | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| TTFTB radical-cation absorption band range | 13500 to 14000 | — | — | Text Range | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |
As-synthesised bulk powder of compound 2 · Powder
Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NIR IVCT band centre | approximately 4000 | — | — | Text Approximate | 8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| Optical band gap Eg from Tauc plot | 1.94 | — | — | Text Rounded Reported | 8563 · Diffuse reflectance spectroscopy · Fig. 7b |
| Higher-energy TTFTB radical-cation absorption band | approximately 21000 | — | — | Text Approximate | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| TTFTB radical-cation absorption band range | 13500 to 14000 | — | — | Text Range | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |
As-synthesised bulk powder of compound 3 · Powder
Powders ground with KBr to 1 wt%; UV-vis-NIR 400-2275 nm, DRIFTS 4200-2000 cm-1; spectra normalised and Tauc fits applied.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NIR IVCT band centre | approximately 4000 | — | — | Text Approximate | 8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| Optical band gap Eg from Tauc plot | 2.02 | — | — | Text Rounded Reported | 8563 · Diffuse reflectance spectroscopy · Fig. 7b |
| Higher-energy TTFTB radical-cation absorption band | approximately 21000 | — | — | Text Approximate | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |
| TTFTB radical-cation absorption band range | 13500 to 14000 | — | — | Text Range | 8562-8563 · Diffuse reflectance spectroscopy · Fig. 7a |