Electrical Transport — Diverse π-π Stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal-organic frameworks

6 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Pressed pellet device of compound 1 · Pellet

Ambient atmosphere at 296 K; at least two pellets from five batches; voltage sweep -0.5 to +0.5 V or -1 to +1 V.

Temperature: 296
Atmosphere: ambient
Geometry: pressed powder between stainless-steel rods, approximately 200 MPa
Context: pristine framework pellet
Measurement source: S5; S25 · Room temperature conductivity measurements · Fig. S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
296 K ambient pressed-pellet average conductivity	2.5(7) x 10^-6	—	(7) x 10^-6	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12
296 K ambient pressed-pellet champion conductivityMarked as a best value within this paper	5.4(3) x 10^-6	—	(3) x 10^-6	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12

Pressed pellet device of compound 2 · Pellet

Ambient atmosphere at 296 K; at least two pellets from five batches; voltage sweep -0.5 to +0.5 V or -1 to +1 V.

Temperature: 296
Atmosphere: ambient
Geometry: pressed powder between stainless-steel rods, approximately 200 MPa
Context: pristine framework pellet
Measurement source: S5; S25 · Room temperature conductivity measurements · Fig. S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
296 K ambient pressed-pellet average conductivity	9(4) x 10^-7	—	(4) x 10^-7	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12
296 K ambient pressed-pellet champion conductivity	2.7(1) x 10^-6	—	(1) x 10^-6	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12

Pressed pellet device of compound 3 · Pellet

Ambient atmosphere at 296 K; at least two pellets from five batches; voltage sweep -0.5 to +0.5 V or -1 to +1 V.

Temperature: 296
Atmosphere: ambient
Geometry: pressed powder between stainless-steel rods, approximately 200 MPa
Context: pristine framework pellet
Measurement source: S5; S25 · Room temperature conductivity measurements · Fig. S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
296 K ambient pressed-pellet average conductivity	1.0(5) x 10^-9	—	(5) x 10^-9	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12
296 K ambient pressed-pellet champion conductivity	3.1(2) x 10^-9	—	(2) x 10^-9	Text Rounded Reported	8561 · Electrical conductivity · Fig. 5; Fig. S12

Pressed pellet device of compound 1 · Pellet

Dynamic vacuum around 1e-5 Torr; screw cell; 250-350 K for 1 and 2, 295-350 K for 3; Arrhenius analysis.

Temperature: 250-350
Atmosphere: dynamic vacuum (~1e-5 Torr)
Geometry: in situ screw cell with Garolite tube and stainless-steel screws, approximately 50 MPa
Context: pristine framework pellet
Measurement source: S5; S27 · Variable temperature conductivity measurements · Fig. S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy Ea	0.28	—	—	Text Rounded Reported	8561 · Electrical conductivity · Fig. 6; Fig. S14
Conductivity response to evacuation	conductivity decreased about 1 order of magnitude under vacuum	—	—	Text Qualitative	8561 · Electrical conductivity · Fig. 6

Pressed pellet device of compound 2 · Pellet

Dynamic vacuum around 1e-5 Torr; screw cell; 250-350 K for 1 and 2, 295-350 K for 3; Arrhenius analysis.

Temperature: 250-350
Atmosphere: dynamic vacuum (~1e-5 Torr)
Geometry: in situ screw cell with Garolite tube and stainless-steel screws, approximately 50 MPa
Context: pristine framework pellet
Measurement source: S5; S27 · Variable temperature conductivity measurements · Fig. S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy Ea	0.2	—	—	Text Rounded Reported	8561 · Electrical conductivity · Fig. 6; Fig. S14
Conductivity response to evacuation	conductivity increased slightly under vacuum	—	—	Text Qualitative	8561 · Electrical conductivity · Fig. 6

Pressed pellet device of compound 3 · Pellet

Dynamic vacuum around 1e-5 Torr; screw cell; 250-350 K for 1 and 2, 295-350 K for 3; Arrhenius analysis.

Temperature: 295-350
Atmosphere: dynamic vacuum (~1e-5 Torr)
Geometry: in situ screw cell with Garolite tube and stainless-steel screws, approximately 50 MPa
Context: pristine framework pellet
Measurement source: S5; S27 · Variable temperature conductivity measurements · Fig. S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy Ea	0.44	—	—	Text Rounded Reported	8561 · Electrical conductivity · Fig. 6; Fig. S14
Conductivity response to evacuation	conductivity decreased about 2 orders of magnitude under vacuum	—	—	Text Qualitative	8561 · Electrical conductivity · Fig. 6