Spectroscopy — Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction

4 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

TNP-MOF crystals · Single Crystal

140 K under N2; NIR irradiation λ ≥ 730 nm; TEOA introduced; TNP linker control

Atmosphere: N2
Context: pristine MOF
Measurement source: 1227-1228 · Mechanisms of NIR-Light-Driven CO2 Reduction · Figure 7B,C; Figure S104

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TNP-MOF radical response	much enhanced π-conjugated cation radical signal upon NIR light irradiation	—	—	Text Qualitative	1228 · Mechanisms · Figure 7C
EPR g value	g = 2.003	—	—	Text Exact Reported	1227 · Mechanisms · Figure 7B
TNP linker EPR control	signal remained unaltered after NIR illumination	—	—	Text Qualitative	S110 · Section 11 In situ EPR · Figure S104

TNP-MOF crystals · Single Crystal

TNP linker and TNP-MOF compared under 510 nm pump; TNP-MOF also under 760 nm pump

Context: pristine MOF
Measurement source: 1226-1227 · Photoinduced Change Separation Characterization · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NIR-induced charge separation	charge separation state can also be induced under NIR light irradiation	—	—	Text Qualitative	1227 · Photoinduced Change Separation Characterization · Figure 6G-I
mof tau1	2.85 ± 0.18 ps	—	± 0.18 ps	Text Exact Reported	1226-1227 · Photoinduced Change Separation Characterization · Figure 6
mof tau2	26.68 ± 1.58 ps	—	± 1.58 ps	Text Exact Reported	1226-1227 · Photoinduced Change Separation Characterization · Figure 6
tnp tau1	3.73 ± 0.36 ps	—	± 0.36 ps	Text Exact Reported	1226-1227 · Photoinduced Change Separation Characterization · Figure 6
tnp tau2	55.67 ± 3.6 ps	—	± 3.6 ps	Text Exact Reported	1226-1227 · Photoinduced Change Separation Characterization · Figure 6
tnp tau3	2172.81 ± 128.58 ps	—	± 128.58 ps	Text Exact Reported	1226-1227 · Photoinduced Change Separation Characterization · Figure 6

TNP-MOF crystals · Single Crystal

MOF samples in DMF suspension; Table S18 reports linker and MOF fluorescence

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TBCP-MOF fluorescence quantum yield	6.1 %	—	—	SI Table Exact Reported	S109 · Table S18 · Table S18
TBML-MOF fluorescence quantum yield	< 0.1 %	—	—	SI Table Approximate	S109 · Table S18 · Table S18
TML-MOF fluorescence quantum yield	2.8 %	—	—	SI Table Exact Reported	S109 · Table S18 · Table S18
TM-MOF fluorescence quantum yield	3.4 %	—	—	SI Table Exact Reported	S109 · Table S18 · Table S18
TNP-MOF fluorescence quantum yield	< 0.1 %	—	—	SI Table Approximate	S109 · Table S18 · Table S18

TNP-MOF crystals · Single Crystal

0.5 mbar CO2 at 300 K; routine XPS before/after NIR and after CO2 photoreduction

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zr XPS feature	184.23 eV	—	—	Text Exact Reported	S111 · Mechanisms/NAP-XPS · Figure 7F; Figure S105
Zr XPS feature	186.66 eV	—	—	Text Exact Reported	S111 · Mechanisms/NAP-XPS · Figure 7F; Figure S105
Zr XPS feature	182.0 eV	—	—	Text Exact Reported	1228 · Mechanisms/NAP-XPS · Figure 7F; Figure S105
Zr XPS feature	182.5 eV	—	—	Text Exact Reported	1228 · Mechanisms/NAP-XPS · Figure 7F; Figure S105