Other — Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction

10 measurement groups · 30 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

ICP-MS/CHNS elemental analysis

Bulk elemental and compositional analysis

TBCP-MOF crystals · Single Crystal

activated at 120 °C under vacuum for 6 h; average of three tests

Context: pristine MOF
Measurement source: S24-S25 · Section 2.7 Element analysis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C content	65.417 ± 0.600 %	—	± 0.600 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
H content	3.197 ± 0.023 %	—	± 0.023 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
N content	4.026 ± 0.111 %	—	± 0.111 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
O content	13.885 ± 0.238 %	—	± 0.238 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
Zr content	13.476 ± 0.228 %	—	± 0.228 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1

ICP-MS/CHNS elemental analysis

Bulk elemental and compositional analysis

TBML-MOF crystals · Single Crystal

activated at 120 °C under vacuum for 6 h; average of three tests

Context: pristine MOF
Measurement source: S24-S25 · Section 2.7 Element analysis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C content	67.910 ± 0.205 %	—	± 0.205 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
H content	4.161 ± 0.004 %	—	± 0.004 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
N content	3.656 ± 0.001 %	—	± 0.001 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
O content	12.838 ± 0.422 %	—	± 0.422 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
Zr content	11.436 ± 0.222 %	—	± 0.222 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1

ICP-MS/CHNS elemental analysis

Bulk elemental and compositional analysis

TML-MOF crystals · Single Crystal

activated at 120 °C under vacuum for 6 h; average of three tests

Context: pristine MOF
Measurement source: S24-S25 · Section 2.7 Element analysis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C content	68.998 ± 0.617 %	—	± 0.617 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
H content	3.560 ± 0.037 %	—	± 0.037 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
N content	3.402 ± 0.030 %	—	± 0.030 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
O content	12.169 ± 0.716 %	—	± 0.716 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
Zr content	11.882 ± 0.163 %	—	± 0.163 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1

ICP-MS/CHNS elemental analysis

Bulk elemental and compositional analysis

TM-MOF crystals · Single Crystal

activated at 120 °C under vacuum for 6 h; average of three tests

Context: pristine MOF
Measurement source: S24-S25 · Section 2.7 Element analysis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C content	69.561 ± 1.230 %	—	± 1.230 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
H content	3.955 ± 0.097 %	—	± 0.097 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
N content	3.388 ± 0.035 %	—	± 0.035 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
O content	11.011 ± 0.085 %	—	± 0.085 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
Zr content	11.124 ± 0.085 %	—	± 0.085 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1

ICP-MS/CHNS elemental analysis

Bulk elemental and compositional analysis

TNP-MOF crystals · Single Crystal

activated at 120 °C under vacuum for 6 h; average of three tests

Context: pristine MOF
Measurement source: S24-S25 · Section 2.7 Element analysis · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C content	71.337 ± 0.907 %	—	± 0.907 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
H content	3.510 ± 0.084 %	—	± 0.084 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
N content	3.238 ± 0.005 %	—	± 0.005 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
O content	11.692 ± 0.948 %	—	± 0.948 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1
Zr content	10.225 ± 0.049 %	—	± 0.049 %	SI Table Exact Reported	S25 · Section 2.7 · Table S1

thermogravimetric analysis

Thermogravimetric analysis

TBCP-MOF crystals · Single Crystal

continuous air; activated samples degassed at 120 °C for 6 h; 10 °C/min

Context: pristine MOF
Measurement source: S20-S23 · Section 2.6 TG analysis · Figures S12-S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability threshold	no obvious weight loss up to 350 °C	—	—	Text Rounded Reported	S20 · Section 2.6 · Figures S12-S17

thermogravimetric analysis

Thermogravimetric analysis

TBML-MOF crystals · Single Crystal

continuous air; activated samples degassed at 120 °C for 6 h; 10 °C/min

Context: pristine MOF
Measurement source: S20-S23 · Section 2.6 TG analysis · Figures S12-S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability threshold	no obvious weight loss up to 350 °C	—	—	Text Rounded Reported	S20 · Section 2.6 · Figures S12-S17

thermogravimetric analysis

Thermogravimetric analysis

TML-MOF crystals · Single Crystal

continuous air; activated samples degassed at 120 °C for 6 h; 10 °C/min

Context: pristine MOF
Measurement source: S20-S23 · Section 2.6 TG analysis · Figures S12-S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability threshold	no obvious weight loss up to 350 °C	—	—	Text Rounded Reported	S20 · Section 2.6 · Figures S12-S17

thermogravimetric analysis

Thermogravimetric analysis

TM-MOF crystals · Single Crystal

continuous air; activated samples degassed at 120 °C for 6 h; 10 °C/min

Context: pristine MOF
Measurement source: S20-S23 · Section 2.6 TG analysis · Figures S12-S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability threshold	no obvious weight loss up to 350 °C	—	—	Text Rounded Reported	S20 · Section 2.6 · Figures S12-S17

thermogravimetric analysis

Thermogravimetric analysis

TNP-MOF crystals · Single Crystal

continuous air; activated samples degassed at 120 °C for 6 h; 10 °C/min

Context: pristine MOF
Measurement source: S20-S23 · Section 2.6 TG analysis · Figures S12-S17

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability threshold	no obvious weight loss up to 350 °C	—	—	Text Rounded Reported	S20 · Section 2.6 · Figures S12-S17