Porosity — Large π-Conjugated Metal-Organic Frameworks for Infrared-Light-Driven CO2Reduction

9 measurement groups · 21 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/BET

Gas sorption and porosity

TBCP-MOF crystals · Single Crystal

77 K; DMF wash 3 days, acetone exchange 1 day, activated at 120 °C under vacuum for 6 h

Temperature: 77
Context: pristine MOF
Measurement source: S38-S44 · Section 4.1 N2 adsorption analysis · Table S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	3831 m2 g-1	—	—	SI Table Exact Reported	S44 · Section 4.1 · Table S7
P/P0 range for BET fit	0.0090-0.0999	—	—	SI Table Range	S44 · Section 4.1 · Table S7
mesoporosity	rising steps in gas uptake indicated mesoporosity	—	—	Text Qualitative	S38 · Section 4.1 · Figures S25-S29

N2 adsorption/BET

Gas sorption and porosity

TBML-MOF crystals · Single Crystal

77 K; DMF wash 3 days, acetone exchange 1 day, activated at 120 °C under vacuum for 6 h

Temperature: 77
Context: pristine MOF
Measurement source: S38-S44 · Section 4.1 N2 adsorption analysis · Table S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	3208 m2 g-1	—	—	SI Table Exact Reported	S44 · Section 4.1 · Table S7
P/P0 range for BET fit	0.0683-0.1628	—	—	SI Table Range	S44 · Section 4.1 · Table S7
mesoporosity	rising steps in gas uptake indicated mesoporosity	—	—	Text Qualitative	S38 · Section 4.1 · Figures S25-S29

N2 adsorption/BET

Gas sorption and porosity

TML-MOF crystals · Single Crystal

77 K; DMF wash 3 days, acetone exchange 1 day, activated at 120 °C under vacuum for 6 h

Temperature: 77
Context: pristine MOF
Measurement source: S38-S44 · Section 4.1 N2 adsorption analysis · Table S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	3213 m2 g-1	—	—	SI Table Exact Reported	S44 · Section 4.1 · Table S7
P/P0 range for BET fit	0.0339-0.1315	—	—	SI Table Range	S44 · Section 4.1 · Table S7
mesoporosity	rising steps in gas uptake indicated mesoporosity	—	—	Text Qualitative	S38 · Section 4.1 · Figures S25-S29

N2 adsorption/BET

Gas sorption and porosity

TM-MOF crystals · Single Crystal

77 K; DMF wash 3 days, acetone exchange 1 day, activated at 120 °C under vacuum for 6 h

Temperature: 77
Context: pristine MOF
Measurement source: S38-S44 · Section 4.1 N2 adsorption analysis · Table S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	2148 m2 g-1	—	—	SI Table Exact Reported	S44 · Section 4.1 · Table S7
P/P0 range for BET fit	0.0090-0.0992	—	—	SI Table Range	S44 · Section 4.1 · Table S7
mesoporosity	rising steps in gas uptake indicated mesoporosity	—	—	Text Qualitative	S38 · Section 4.1 · Figures S25-S29

N2 adsorption/BET

Gas sorption and porosity

TNP-MOF crystals · Single Crystal

77 K; DMF wash 3 days, acetone exchange 1 day, activated at 120 °C under vacuum for 6 h

Temperature: 77
Context: pristine MOF
Measurement source: S38-S44 · Section 4.1 N2 adsorption analysis · Table S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	1156 m2 g-1	—	—	SI Table Exact Reported	S44 · Section 4.1 · Table S7
P/P0 range for BET fit	0.0051-0.0752	—	—	SI Table Range	S44 · Section 4.1 · Table S7
mesoporosity	rising steps in gas uptake indicated mesoporosity	—	—	Text Qualitative	S38 · Section 4.1 · Figures S25-S29

CO2 adsorption isotherms

Gas sorption and porosity

TBCP-MOF crystals · Single Crystal

273 and 298 K at up to 1 atm

Context: pristine MOF
Measurement source: S45 · Section 4.2 CO2 adsorption analysis · Figures S35-S37

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake	high CO2 uptake at 273 and 298 K at 1 atm	—	—	Text Qualitative	1223 · Preparation and Characterization of MOFs · Figures S35-S37

CO2 adsorption isotherms

Gas sorption and porosity

TML-MOF crystals · Single Crystal

273 and 298 K at up to 1 atm

Context: pristine MOF
Measurement source: S45 · Section 4.2 CO2 adsorption analysis · Figures S35-S37

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake	high CO2 uptake at 273 and 298 K at 1 atm	—	—	Text Qualitative	1223 · Preparation and Characterization of MOFs · Figures S35-S37

CO2 adsorption isotherms

Gas sorption and porosity

TNP-MOF crystals · Single Crystal

273 and 298 K at up to 1 atm

Context: pristine MOF
Measurement source: S45 · Section 4.2 CO2 adsorption analysis · Figures S35-S37

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CO2 uptake	high CO2 uptake at 273 and 298 K at 1 atm	—	—	Text Qualitative	1223 · Preparation and Characterization of MOFs · Figures S35-S37

post-photocatalysis N2 adsorption, PXRD, SEM/TEM-EDS

X-ray diffraction and scattering Scanning electron microscopy Transmission electron microscopy Elemental microanalysis and mapping Gas sorption and porosity

TNP-MOF after 48 h photocatalytic test · Powder

after 48 h photocatalytic test

Context: pristine MOF
Measurement source: S87-S90 · Section 7 Stability of TNP-MOF · Figures S72-S77

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area after 48 h	736 m2/g	—	—	Text Exact Reported	S87 · Section 7 · Figure S73
BET area retention after 48 h	736/1156 = 63.7%	—	—	Calculated From Reported Rounded Reported	S87 · Section 7 · Figures S34 and S73
PXRD stability	crystal structure well maintained	—	—	Text Qualitative	1224 · NIR-Light-Driven CO2Reduction Performance · Figure S75