Measurement evidence
Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation · Guo Z., Panda D.K., Gordillo M.A. et al. · ACS Applied Materials and Interfaces · 2017 · 32413-32417
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
TTF-doped DSNDI-based MOF-74 powder · Powder
EPR spectra of undoped and TTF-doped MOF-74 compared.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Pristine MOF EPR response | EPR silent | — | — | Text Qualitative | p003 / article p.32415 · Main text · Figure S6 |
| TTF-loaded MOF EPR response | EPR active; coexistence of TTF radical cations and DSNDI radical anions | — | — | Text Qualitative | p003 / article p.32415 · Main text · Figure S6 |
Activated DSNDI-based MOF-74 powder · Powder
DSNDI-based MOF-74 spectra compared with DSNDI ligand.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| NMR/FT-IR agreement with ligand | solid-state 13C NMR and FT-IR spectra of the MOF are in excellent agreement with DSNDI ligand | — | — | Text Qualitative | p002 / article p.32414 · Main text · Figures S1 and S2 |
DSNDI ligand reference · Unknown
Ligand reference spectrum; optical band gap determined from onset of longest-wavelength absorption.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| DSNDI optical band gapMarked as a best value within this paper | ~2.5 eV from onset at ~500 nm | — | — | Text Approximate | p002-p003 / article pp.32414-32415 · Main text · Figure 2b |
Activated DSNDI-based MOF-74 powder · Powder
UV-vis-NIR spectra of MOF-74 in absence of TTF guests; optical band gap from absorption onset.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF UV-vis absorption maximum | lambda_max = 410 nm | — | — | Text Exact Reported | p003 / article p.32415 · Main text · Figure 2b |
| Optical band gapMarked as a best value within this paper | 2.1 eV from onset at 600 nm | — | — | Text Rounded Reported | p003 / article p.32415 · Main text · Figure 2b |
TTF-doped DSNDI-based MOF-74 powder · Powder
MOF-74 after soaking in TTF solution for 2 days; new charge-transfer band used to estimate optical band gap.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct electrical conductivity measurement | not reported | — | — | Qualitative Qualitative | p001 / article p.32413 · Abstract |
| Optical band-gap lowering vs parentMarked as a best value within this paper | 1.1 eV lower than parent material | — | — | Text Rounded Reported | p003 / article p.32415 · Main text · Figure 2b |
| Charge-transfer band centre | centered at 900 nm | — | — | Text Rounded Reported | p003 / article p.32415 · Main text · Figure 2b |
| Optical band gap after TTF loadingMarked as a best value within this paper | ~1 eV from CT-band onset at 1250 nm | — | — | Text Approximate | p003 / article p.32415 · Main text · Figure 2b |