Electrochemistry Application — Lowering Band Gap of an Electroactive Metal-Organic Framework via Complementary Guest Intercalation

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

DSNDI ligand reference · Unknown

First reduction of DSNDI ligand, 1 mM in 0.1 M Bu4NPF6/DMF, vs Ag/AgCl.

Geometry: Ag/AgCl reference electrode, Pt counter electrode, Pt or glassy-carbon disc working electrode
Context: Molecular acceptor reference
Measurement source: S-7 / render p007 · Figure S5 caption · Figure S5A

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DSNDI reduction potentialMarked as a best value within this paper	ERed = -450 mV vs Ag/AgCl	-0.45 V vs Ag/AgCl	—	Text Exact Reported	p002 / article p.32414 · Main text · Figure S5
DSNDI LUMO estimateMarked as a best value within this paper	-3.9 eV	—	—	Text Rounded Reported	p003 / article p.32415 · Main text

TTF guest reference · Unknown

First oxidation of TTF guest, 1 mM in 0.1 M Bu4NPF6/DMF, vs Ag/AgCl.

Geometry: Ag/AgCl reference electrode, Pt counter electrode, Pt or glassy-carbon disc working electrode
Context: Molecular donor reference
Measurement source: S-7 / render p007 · Figure S5 caption · Figure S5B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TTF oxidation potentialMarked as a best value within this paper	EOx = +460 mV vs Ag/AgCl	0.46 V vs Ag/AgCl	—	Text Exact Reported	p003 / article p.32415 · Main text · Figure S5
TTF HOMO estimateMarked as a best value within this paper	-4.8 eV	—	—	Text Rounded Reported	p003 / article p.32415 · Main text