Measurement evidence
Structure and Electrical Transport Properties of Metal Cate-Cholate Frameworks: The Metal Center Matters† · Yang M., Zhu R., Chen X. et al. · Chinese Journal of Chemistry · 2026 · 311-318
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Ca-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ca-HHTP EPR signal assignment | g about 2.00 radical signal | 2 g factor | — | Text Approximate | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Ca-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ca-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Ca-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ca-HHTP direct optical band gap from Tauc plot | 1.27 eV | 1.27 eV | — | Figure Axis Approximate | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Ca-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ca 2p1/2 binding energy | 350.7 eV | 350.7 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
| Ca 2p3/2 binding energy | 347.1 eV | 347.1 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
Co-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co-HHTP EPR signal assignment | no prominent EPR signal | — | — | Qualitative Qualitative | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Co-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Co-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co-HHTP direct optical band gap from Tauc plot | 1.40 eV | 1.4 eV | — | Figure Axis Approximate | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Co-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Cu-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-HHTP EPR signal assignment | broad g = 2.1 signal | 2.1 g factor | — | Text Approximate | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Cu-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Cu-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-HHTP direct optical band gap from Tauc plotMarked as a best value within this paper | 1.09 eV | 1.09 eV | — | Text Rounded Reported | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Cu-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-HHTP ICP-AES copper content calculated | Cu calculated 23.05% | — | — | Text Exact Reported | SI p.S7 · Synthesis of Cu-HHTP MOF |
| Cu-HHTP ICP-AES copper content found | Cu found 23.41% | — | — | Text Exact Reported | SI p.S7 · Synthesis of Cu-HHTP MOF |
| Cu 2p3/2 Cu+ component binding energy | 932.5 eV | 932.5 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
| Cu 2p3/2 Cu2+ component binding energy | 934.9 eV | 934.9 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
Mg-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Mg-HHTP EPR signal assignment | g about 2.00 radical signal | 2 g factor | — | Text Approximate | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Mg-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Mg-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Mg-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Mg-HHTP direct optical band gap from Tauc plot | 1.26 eV | 1.26 eV | — | Figure Axis Approximate | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Mg-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Mg 2p binding energy assigned to Mg2+ | 50.3 eV | 50.3 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
| O 1s C=O component binding energy common to all M-HHTP | 531.2 eV | 531.2 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
| O 1s C-O component binding energy common to all M-HHTP | 532.8 eV | 532.8 eV | — | Text Exact Reported | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3; Figure S10 |
Ni-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni-HHTP EPR signal assignment | weak sharp g = 2.00 signal | 2 g factor | — | Text Approximate | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Ni-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Ni-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni-HHTP direct optical band gap from Tauc plot | 1.49 eV | 1.49 eV | — | Figure Axis Approximate | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Ni-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Zn-HHTP powder sample · Powder
JEOL JES-FA200 ESR spectrometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Zn-HHTP EPR signal assignment | g around 2.00 radical signal | 2 g factor | — | Text Approximate | main p.4, article p.314 · Electronic structure of M-HHTP MOFs · Figure 3g-l |
Zn-HHTP powder sample · Powder
Bruker TENSOR II using KBr pellet method.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Zn-HHTP FTIR coordination evidence | Free HHTP OH stretch disappeared; band around 1640 cm^-1 assigned to C=O stretch. | 1640 cm^-1 | — | Text Rounded Reported | main p.2, article p.312 · Preparation and structural characterizations · Figure S3-S4 |
Zn-HHTP film sample · Thin Film
Transmission mode using integrating sphere detector and 20 nm slit width.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Zn-HHTP direct optical band gap from Tauc plot | 1.48 eV | 1.48 eV | — | Figure Axis Approximate | SI p.S15 · Ultraviolet-Visible-Near Infrared Spectrum · Figure S12 |
Zn-HHTP powder sample · Powder
Thermo ESCALAB 250Xi, monochromatized Al Kalpha hnu = 1486.6 eV, pass energy 30 eV, 150 W, 500 um spot; C 1s calibrated at 284.80 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|