Spectroscopy — Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing Process

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

MASS-PRC Ni3(HITP)2 thin film · Thin Film

Chemical bonding comparison of precursor film and post-treated Ni3(HITP)2 film.

Context: pre-treatment precursor compared with pristine Ni3(HITP)2 thin film
Measurement source: 4 · 2.2 Characterizations of Ni3(HITP)2 Thin Film · Figure 2; Figures S8-S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR N-H stretch decrease range	3550-3250 cm-1 N-H stretches decrease after deprotonation	—	—	Text Range	4 · 2.2 Characterizations of Ni3(HITP)2 Thin Film · Figure 2c
Raman ID/IG after treatment	1.04	—	—	Text Exact Reported	23 · Figure S9 Discussion · Figure S9
Raman ID/IG before treatment	1.18	—	—	Text Exact Reported	23 · Figure S9 Discussion · Figure S9
Before-treatment Cl 2p peaks	199.3 and 197.7 eV	—	—	Text Exact Reported	4 · 2.2 Characterizations of Ni3(HITP)2 Thin Film · Figure 2e
After-treatment Ni-N4 N 1s peak	398.9 eV	—	—	Text Exact Reported	4 · 2.2 Characterizations of Ni3(HITP)2 Thin Film · Figure 2f

MASS-PRC Ni3(HITP)2 thin film · Thin Film

Thin film and bulk powder exposed to H2S and analysed for adsorbate and linker redox evidence.

Temperature: room temperature
Atmosphere: H2S exposure
Context: pristine Ni3(HITP)2 film and powder; Ni-HHTP analogue control
Measurement source: 6 · 2.3 Sensing Characterizations · Figure 4c,d; Figures S24-S26

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HITP-centred radical EPR g value after H2S exposure	g = 1.99	—	—	Text Exact Reported	39 · Figure S25 Discussion · Figure S25
Ni3(HITP)2 sulfite:sulfide S 2p ratio	sulfite : sulfide = 1 : 3.57	—	—	Text Exact Reported	40 · Figure S26 Discussion · Figure S26
Ni-HHTP sulfite:sulfide S 2p ratio	sulfite : sulfide = 1 : 0.75	—	—	Text Exact Reported	40 · Figure S26 Discussion · Figure S26
Sulfide S 2p3/2 binding energy after H2S exposure	163.8 eV	—	—	Text Exact Reported	6 · 2.3 Sensing Characterizations · Figure 4c,d
Sulfite S 2p3/2 binding energy after H2S exposure	167.7 eV	—	—	Text Exact Reported	6 · 2.3 Sensing Characterizations · Figure 4c,d