Sensing Application — Large-Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal–Organic Framework Thin Films via a Microfluidic-Based Solution Shearing Process

6 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Bulk Ni3(HITP)2 powder drop-cast sensor control · Powder

5 ppm H2S, room temperature, nitrogen atmosphere; drop-cast bulk-powder control.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Bulk Ni3(HITP)2 crystallite size range	about 100-300 nm	—	—	Text Range	6 · 2.3 Sensing Characterizations · Figure S23
Bulk Ni3(HITP)2 response to 5 ppm H2S	dR/R0 = 69%	—	—	Text Exact Reported	5 · 2.3 Sensing Characterizations · Figure 4a

Ni3(HITP)2 thin-film chemiresistive sensor on alumina · Electrode

5 ppm H2S, room temperature, nitrogen atmosphere; resistance response [(dR/R0) x 100].

Temperature: room temperature
Atmosphere: N2
Geometry: alumina substrate with interdigitated gold electrode; 150 um gap
Context: pristine thin-film target compared with bulk Ni3(HITP)2 powder control
Measurement source: 5 · 2.3 Sensing Characterizations · Figure 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thin-film response enhancement over bulk	30.2 times greater	—	—	Text Exact Reported	5 · 2.3 Sensing Characterizations · Figure 4a
Thin-film Ni3(HITP)2 response to 5 ppm H2SMarked as a best value within this paper	dR/R0 = 2085%	—	—	Text Exact Reported	5 · 2.3 Sensing Characterizations · Figure 4a

Ni3(HITP)2 thin-film chemiresistive sensor on alumina · Electrode

H2S concentrations 0.1-10 ppm; slope from linear response fit; noise from 60 min baseline under nitrogen after 3 h stabilisation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H2S calibration R2	R2 = 0.98	—	—	Text Exact Reported	7 · 2.3 Sensing Characterizations · Figure 4e
Experimental H2S detection limit	Experimental: < 0.1 ppm	—	<	SI Table Approximate	14 · Table S4 · Table S4
Calculated H2S limit of detectionMarked as a best value within this paper	3 ppb / 0.003 ppm	3 ppb	—	Text Exact Reported	7 · 2.3 Sensing Characterizations · Table S4
H2S sensitivity from main textMarked as a best value within this paper	Slope = 362 % ppm-1	—	R2 = 0.98	Text Exact Reported	7 · 2.3 Sensing Characterizations · Figure 4e
Average baseline noise	0.327%	—	—	Text Exact Reported	9 · Chemiresistive gas sensing measurement · Figure S30

Ni3(HITP)2 thin-film chemiresistive sensor on alumina · Electrode

10 cycles; each cycle 30 min exposure to 1 ppm H2S and 30 min recovery.

Temperature: room temperature
Atmosphere: N2
Geometry: chemiresistive interdigitated electrode device
Context: pristine Ni3(HITP)2 thin-film sensor
Measurement source: 7 · 2.3 Sensing Characterizations · Figure 4g; Figure S28

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Dosimetric cyclic H2S response	10 cycles, 30 min exposure to 1 ppm H2S and 30 min recovery per cycle; repeated response increase reflects cumulative dose	—	—	Caption Qualitative	6 · Figure 4 caption · Figure 4g

Ni3(HITP)2 thin-film chemiresistive sensor on alumina · Electrode

5 ppm H2S and 5 ppm interfering gases NO, HCHO, CO, CH4, C2H6, H2, and C2H2.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H2S selectivity over interfering gases	response two orders of magnitude greater for H2S than NO, HCHO, CO, CH4, C2H6, H2, and C2H2	—	—	Text Qualitative	7 · 2.3 Sensing Characterizations · Figure 4f

Flexible Ni3(HITP)2 thin-film sensor · Electrode

5 ppm H2S under relative humidity 80%, comparing thin film and bulk.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Bulk response to 5 ppm H2S at RH 80%	dR/R0 = 26%	—	—	Text Exact Reported	7 · 2.3 Sensing Characterizations · Figure 5e
Thin-film response to 5 ppm H2S at RH 80%	dR/R0 = 197%	—	—	Text Exact Reported	7 · 2.3 Sensing Characterizations · Figure 5e