Spectroscopy — Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc

5 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Complex 2 compressed pellet · Pellet

Powder ESR at room temperature and liquid nitrogen temperature; TCNE calibration.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 2 room-temperature ESR gavg	gavg 2.097; gparallel 2.203; FWHparallel 230 G; gperp 2.044; FWHperp 100 G; frequency 9.1 GHz	—	—	Table Exact Reported	p012 / 4240 · Table 2 · Table 2

Complex 4 compressed pellet · Pellet

Powder ESR at room temperature; TCNE calibration.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 4 room-temperature ESR gavg	gavg 2.098; gparallel 2.188; FWHparallel 290 G; gperp 2.054; FWHperp 148 G; frequency 9.1 GHz	—	—	Table Exact Reported	p012 / 4240 · Table 2 · Table 2

Complex 7 compressed pellet · Pellet

Powder ESR at room temperature; TCNE calibration.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 7 room-temperature ESR gavg	Aparallel 145 G; gavg 2.127; gparallel 2.284; FWHparallel 320 G; gperp 2.048; FWHperp 90 G; frequency 9.5 GHz	—	—	Table Exact Reported	p012 / 4240 · Table 2 · Table 2

Complex 2 compressed pellet · Pellet

IR spectra from 4000 to 400 cm^-1; Table S1 reports assigned bands for 1-7.

Geometry: KBr disc
Context: all complexes; sample_key points to representative complex 2 to satisfy schema
Measurement source: SI p1 · Table S1 · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 2 IR bands	nu(OH) 3470 bs; nu_as(NH2/NH) 3282 m; nu_as(C=O) 1653 ms; nu(C=C) ring 1542 sh; betaNH2 1494 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1
Complex 3 IR bands	nu(OH) 3470 bs; nu_as(NH2/NH) 3301 s; nu_as(C=O) 1657 ms; nu(C=C) ring 1525 vs; betaNH2 1525 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1
Complex 4 IR bands	nu(OH) 3451 bs; nu_as(NH2/NH) 3321 sh; nu_as(C=O) 1611 ms; nu(C=C) ring 1518 vs; betaNH2 1518 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1
Complex 5 IR bands	nu(OH) 3421 bs; nu_as(NH2/NH) 3270 sh; nu_as(C=O) 1584 ms; nu(C=C) ring 1508 vs; betaNH2 1508 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1
Complex 6 IR bands	nu(OH) 3427 bs; nu_as(NH2/NH) 3324 sh; nu_as(C=O) 1600 sh; nu(C=C) ring 1516 vs; betaNH2 1516 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1
Complex 7 IR bands	nu(OH) 3449 bs; nu_as(NH2/NH) 3325 sh; nu_as(C=O) 1623 sh; nu(C=C) ring 1517 vs; betaNH2 1517 vs	—	—	SI Table Exact Reported	SI p1 · Table S1 · Table S1

Complex 2 compressed pellet · Pellet

Magnetic susceptibility at room temperature on powdered samples; electronic absorption as Nujol mulls.

Temperature: room temperature
Geometry: powder/Nujol mull
Context: all complexes; sample_key points to representative complex 2 to satisfy schema
Measurement source: p008 / 4236 · 3.4 · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Complex 2 magnetic moment	1.63 BM	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1
Complex 3 magnetic behaviour	Diamagnetic	—	—	Table Qualitative	p008 / 4236 · Table 1 · Table 1
Complex 4 magnetic moment	2.03 BM	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1
Complex 5 magnetic moment	1.96 BM	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1
Complex 6 magnetic moment	1.88 BM	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1
Complex 7 magnetic moment	1.92 BM	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1
Complex 6 electronic absorption bands	17391, 26317, 28169, 31746 cm^-1	—	—	Table Exact Reported	p008 / 4236 · Table 1 · Table 1