Vague recipeSource: Main
Route 1: Unknown
p003 / 4231 · 2.2.1
Metal precursorsNot reported in this paper; stated to follow earlier reference [11].
Linker precursorsdadb, implied by formula; detailed recipe not reported here.
Synthesis evidence
Synthesis, characterization, and solid state electrical conductivity of coordination polymers with copper and zinc
Prasad R.L., Kushwaha A. · Journal of Coordination Chemistry · 2012 · 4230-4244
6 structured synthesis routes
Completeness describes how fully the route could be reconstructed from the main article and supporting information.
Vague recipeSource: Main
Route 2: Unknown
p003 / 4231 · 2.2.1
Metal precursorsNot reported in this paper; stated to follow earlier reference [11].
Linker precursorsdadb, implied by formula; detailed recipe not reported here.
Vague recipeSource: Main
Route 3: Unknown
p003 / 4231 · 2.2.1
Metal precursorsNot reported in this paper; stated to follow earlier reference [11].
Linker precursorsdadb, implied by formula; detailed recipe not reported here.
Complete recipeSource: Main
Route 4: Other
p004 / 4232 · 2.2.2
Metal precursorsZnSO4.7H2O (0.431 g, 1.5 mmol); CuSO4.5H2O (0.125 g, 0.5 mmol)
Linker precursorsdadb (0.414 g, 2 mmol)
Solvents40 mL pink 50% ethanolic solution; purification mixture 25% ethanol, 25% acetone, 5% DMF, 45% distilled water
AdditivesKOH (0.224 g, 4 mmol)
Atmospherenot stated
Temperatureroom temperature after water-bath digestion; exact water-bath temperature not stated
Time0.5 h dropwise addition; 5 h stirring; 0.5 h water-bath digestion; 1 h purification stirring
Work-upFiltered using suction, washed with distilled water; purified by stirring in solvent mixture, filtered, washed with distilled water thrice followed by ethanol.
ActivationDried under vacuum over anhydrous CaCl2.
Scalability contextBatch used 2 mmol dadb and stoichiometric Cu/Zn sulfate salts.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | ZnSO4.7H2O | 0.431 g, 1.5 mmol | p004 / 4232 · 2.2.2 |
| Metal Source | CuSO4.5H2O | 0.125 g, 0.5 mmol | p004 / 4232 · 2.2.2 |
| Linker | dadb | 0.414 g, 2 mmol | p004 / 4232 · 2.2.2 |
| Base | KOH | 0.224 g, 4 mmol | p004 / 4232 · 2.2.2 |
| Solvent | 50% ethanolic solution | 40 mL · 50% | p004 / 4232 · 2.2.2 |
Complete recipeSource: Main
Route 5: Other
p004 / 4232 · 2.2.3
Metal precursorsZnSO4.7H2O (0.503 g, 1.75 mmol); CuSO4.5H2O (0.062 g, 0.25 mmol)
Linker precursorsdadb (0.414 g, 2 mmol)
Solvents40 mL pink 50% ethanolic solution; same purification procedure as complex 5
AdditivesKOH (0.224 g, 4 mmol)
Atmospherenot stated
Temperaturesame as route 5; exact water-bath temperature not stated
Time0.5 h dropwise addition; otherwise same as route 5
Work-upSame as synthesis of 5.
ActivationSame as synthesis of 5; dried under vacuum over anhydrous CaCl2.
Scalability contextBatch used 2 mmol dadb with Zn:Cu salt ratio 1.75:0.25 mmol.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | ZnSO4.7H2O | 0.503 g, 1.75 mmol | p004 / 4232 · 2.2.3 |
| Metal Source | CuSO4.5H2O | 0.062 g, 0.25 mmol | p004 / 4232 · 2.2.3 |
| Linker | dadb | 0.414 g, 2 mmol | p004 / 4232 · 2.2.3 |
| Base | KOH | 0.224 g, 4 mmol | p004 / 4232 · 2.2.3 |
| Solvent | 50% ethanolic solution | 40 mL · 50% | p004 / 4232 · 2.2.3 |
Vague recipeSource: Main
Route 6: Unknown
p004 / 4232 · 2.2.1
Metal precursorsNot reported in this paper; stated to follow earlier reference [11].
Linker precursorsdadb, implied by formula; detailed recipe not reported here.