Spectroscopy — A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity

Measurement evidence

Spectroscopy

A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity · Hu J.-J., Li Y.-G., Wen H.-R. et al. · Dalton Transactions · 2021 · 14714-14723

2 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state EPR

2-Dy · Powder

X-band, 9.05 GHz, room temperature; Bruker EMX.

Temperature
room temperature
Geometry
solid-state powder
Context
iodine-oxidised framework
Measurement source
14718 · General characterization · Fig. S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EPR g value2.002Text
Exact Reported
14718 · General characterization · Fig. S11

X-ray photoelectron spectroscopy

2-Tb · Powder

I 3d XPS survey/deconvolution for 2-Tb and 2-Dy.

Geometry
powder
Context
iodine-oxidised framework
Measurement source
14718 · General characterization · Fig. S12-S14
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
I3- I 3d5/2 binding energy in 2-Dy630.0 eVText
Exact Reported
14718 · General characterization · Fig. S14
I3- I 3d5/2 binding energy in 2-Tb629.8 eVText
Exact Reported
14718 · General characterization · Fig. S13