Diffraction Structure — A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity

5 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

2-Dy · Powder

PXRD patterns for 1-Ln and 2-Ln recorded with Cu target; simulated PXRD from single-crystal data.

Geometry: powder
Context: pristine and iodine-oxidised frameworks
Measurement source: 14715-14718 · Materials and instrumentation; General characterization · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Framework retained after oxidation by PXRD	diffraction peaks of 1-Ln and 2-Ln are basically the same	—	—	Text Qualitative	14718 · General characterization · Fig. S3

1-Dy · Powder

293 K; Bruker D8 QUEST; CCDC 2043197.

Temperature: 293
Geometry: single crystal
Context: pristine framework
Measurement source: 14716-14717 · Single-crystal structure determination · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R1 refinement factor	0.0539	—	—	Table Exact Reported	data_1-Dy · _refine_ls_R_factor_gt
Unit-cell volume	10364.6(5) A3	—	(5)	Table Exact Reported	14717 · Crystal structures · Table 1

1-Er · Powder

293 K; Bruker D8 QUEST; CCDC 2043198.

Temperature: 293
Geometry: single crystal
Context: pristine framework
Measurement source: 14716-14717 · Single-crystal structure determination · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R1 refinement factor	0.0562	—	—	Table Exact Reported	data_1-Er · _refine_ls_R_factor_gt
Unit-cell volume	10312.2(4) A3	—	(4)	Table Exact Reported	14717 · Crystal structures · Table 1

1-Gd · Powder

293 K; Bruker D8 QUEST; CCDC 2043195.

Temperature: 293
Geometry: single crystal
Context: pristine framework
Measurement source: 14716-14717 · Single-crystal structure determination · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R1 refinement factor	0.0668	—	—	Table Exact Reported	data_1-Gd · _refine_ls_R_factor_gt
Unit-cell volume	10450(4) A3	—	(4)	Table Exact Reported	14717 · Crystal structures · Table 1

1-Tb · Powder

293 K; Bruker D8 QUEST; CCDC 2043196.

Temperature: 293
Geometry: single crystal
Context: pristine framework
Measurement source: 14716-14717 · Single-crystal structure determination · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R1 refinement factor	0.0720	—	—	Table Exact Reported	data_1-Tb · _refine_ls_R_factor_gt
Unit-cell volume	10447.4(6) A3	—	(6)	Table Exact Reported	14717 · Crystal structures · Table 1