Electrochemistry Application — A family of lanthanide metal-organic frameworks based on a redox-active tetrathiafulvalene-dicarboxylate ligand showing slow relaxation of magnetisation and electronic conductivity

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state cyclic voltammetry

Voltammetry

1-Dy · Powder

Three forward scans and scan-rate series from 50-400 mV s-1; potentials vs Fc/Fc+.

Geometry: glassy carbon electrode
Context: pristine framework
Measurement source: 14718-14719 · Cyclic voltammetry · Fig. 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TTF/TTF radical cation redox peak	0.15 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. 2
TTF radical cation/TTF dication redox peak	0.50 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. 2

Solid-state cyclic voltammetry

Voltammetry

1-Er · Powder

Same setup as 1-Dy; redox potentials reported vs Fc/Fc+.

Geometry: glassy carbon electrode
Context: pristine framework
Measurement source: 14718 · Cyclic voltammetry · Fig. S5; Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TTF/TTF radical cation redox peak	0.12 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5
TTF radical cation/TTF dication redox peak	0.51 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5

Solid-state cyclic voltammetry

Voltammetry

1-Gd · Powder

Sample dispersed in ethanol and dropped on glassy carbon; SCE reference; Pt auxiliary; Fc/Fc+ internal standard; 0.1 mol L-1 tetrabutylammonium hexafluorophosphate in CH3CN.

Geometry: glassy carbon electrode
Context: pristine framework
Measurement source: 14718 · Cyclic voltammetry · Fig. S5; Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TTF/TTF radical cation redox peak	0.15 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5
TTF radical cation/TTF dication redox peak	0.51 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5

Solid-state cyclic voltammetry

Voltammetry

1-Tb · Powder

Same setup as 1-Dy; redox potentials reported vs Fc/Fc+.

Geometry: glassy carbon electrode
Context: pristine framework
Measurement source: 14718 · Cyclic voltammetry · Fig. S5; Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TTF/TTF radical cation redox peak	0.13 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5
TTF radical cation/TTF dication redox peak	0.50 V vs Fc/Fc+	—	—	Text Rounded Reported	14718 · Cyclic voltammetry · Fig. S5