Spectroscopy — Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

2DCP-NiPc powder · Powder

Room-temperature and temperature-dependent EPR; spin count per unit cell.

Temperature: 298
Context: pristine
Measurement source: S37-S38 · Supplementary Figures 43-44 · Supplementary Figs. 43-44

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-NiPc EPR spin number	0.21 per unit cell (per phthalocyanine) at 298 K	—	—	Text Exact Reported	S37-S38 · Supplementary Figure 44 discussion · Supplementary Fig. 44

2DCP-CuPc powder · Powder

Spectroscopic verification of imidazole ring formation and conjugation; 2DCP-MPc powder samples.

Context: pristine
Measurement source: 881-882 · Synthesis and characterizations of 2DCPs · Supplementary Figs. 36 and 41

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-MPc FTIR C=N stretch	1660 cm-1	—	—	Text Exact Reported	881-882 · Synthesis and characterizations of 2DCPs · Supplementary Fig. 36
2DCP-MPc FTIR C=O stretch	1701 cm-1	—	—	Text Exact Reported	881-882 · Synthesis and characterizations of 2DCPs · Supplementary Fig. 36
2DCP-MPc Raman C=C ring stretching range	1582-1603 cm-1	—	—	Text Range	882 · Synthesis and characterizations of 2DCPs · Supplementary Fig. 41

2DCP-CuPc thin film on fused silica · Thin Film

Film on fused silica; spectra corrected to determine optical bandgap.

Temperature: 298
Geometry: thin film on fused silica
Context: pristine
Measurement source: 883-884 · Optical absorption and time-resolved THz spectroscopy · Fig. 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-CuPc optical bandgapMarked as a best value within this paper	1.28 eV	—	—	Text Exact Reported	883-884 · Optical absorption and time-resolved THz spectroscopy · Fig. 4a
2DCP-MPc film Q-band absorption range	550-1000 nm	—	—	Text Range	883-884 · Optical absorption and time-resolved THz spectroscopy · Fig. 4a

2DCP-NiPc thin film on fused silica · Thin Film

Film on fused silica; spectra corrected to determine optical bandgap.

Temperature: 298
Geometry: thin film on fused silica
Context: pristine
Measurement source: 883-884 · Optical absorption and time-resolved THz spectroscopy · Fig. 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-NiPc optical bandgap	1.33 eV	—	—	Text Exact Reported	883-884 · Optical absorption and time-resolved THz spectroscopy · Fig. 4a