Diffraction Structure — Exceptionally high charge mobility in phthalocyanine-based poly(benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PXRD after solvent/acid/base soaking

X-ray diffraction and scattering

2DCP-CuPc powder · Powder

Soaked at room temperature for 24 h in acetone, ethanol, tetrahydrofuran, dimethylformamide, 0.5 M H2SO4 and 1.0 M NaOH; PXRD recorded in reflection geometry.

Temperature: 298
Context: pristine_control
Measurement source: S39 · Supplementary Figure 45 caption · Supplementary Fig. 45

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-CuPc PXRD retained after solvent, acid and base treatments	retained PXRD patterns after 24 h soaking in acetone, ethanol, THF, DMF, 0.5 M H2SO4 and 1.0 M NaOH	—	—	Qualitative Qualitative	S39 · Supplementary Figure 45 caption · Supplementary Fig. 45

Powder X-ray diffraction and Pawley refinement

X-ray diffraction and scattering

2DCP-CuPc powder · Powder

Cu-Kalpha radiation; transmission geometry; room temperature; Pawley refinement over ca. 2.5-40 deg 2theta.

Temperature: 298
Context: pristine
Measurement source: 881 · Synthesis and characterizations of 2DCPs · Fig. 2c; Supplementary Fig. 29

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-CuPc Pawley Rp	Rp = 2.26%	—	—	Caption Exact Reported	S28-S29 · Supplementary Figure 29 · Supplementary Fig. 29
2DCP-CuPc Pawley Rwp	Rwp = 3.39%	—	—	Caption Exact Reported	S28-S29 · Supplementary Figure 29 · Supplementary Fig. 29
2DCP-CuPc PXRD peak positions	2theta peaks at 4.62, 8.18, 12.17 and 26.82 deg; assigned to (100), (200), (400) and (002)	—	—	Text Exact Reported	881 · Synthesis and characterizations of 2DCPs · Fig. 2c

Powder X-ray diffraction and Pawley refinement

X-ray diffraction and scattering

2DCP-NiPc powder · Powder

Cu-Kalpha radiation; transmission geometry; room temperature; Pawley refinement over ca. 2.5-40 deg 2theta.

Temperature: 298
Context: pristine
Measurement source: 881 · Synthesis and characterizations of 2DCPs · Fig. 2c; Supplementary Figs. 30-31

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
2DCP-NiPc (100) PXRD peak	4.72 deg	—	—	Caption Exact Reported	S29 · Supplementary Figure 31 · Supplementary Fig. 31
2DCP-NiPc Pawley Rp	Rp = 3.28%	—	—	Caption Exact Reported	S29 · Supplementary Figure 30 · Supplementary Fig. 30
2DCP-NiPc Pawley Rwp	Rwp = 4.73%	—	—	Caption Exact Reported	S29 · Supplementary Figure 30 · Supplementary Fig. 30