Spectroscopy — Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ac@[Ca-NDI] MOCF powder · Powder

DMPO used for superoxide and hydroxyl radicals; TEMP used for singlet oxygen; dark and illuminated conditions.

Context: Target MOCF photocatalytic mechanism.
Measurement source: main pp.6-7, article pp.4449-4450 · Results and discussion · Fig. 5a-c and Fig. S27

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Argon atmosphere suppresses phenol degradation	O2 had a significant role in the reaction	—	—	Qualitative Qualitative	main p.6, article p.4449 · Results and discussion · Fig. S28
Phenol conversion with benzoquinone scavenger	13.5%	—	—	Figure Axis Rounded Reported	main p.7, article p.4450 · Results and discussion · Fig. 5e
Phenol conversion without scavenger	60.9%	—	—	Figure Axis Rounded Reported	main p.7, article p.4450 · Results and discussion · Fig. 5e
Phenol conversion with TEOA scavenger	4.6%	—	—	Figure Axis Rounded Reported	main p.7, article p.4450 · Results and discussion · Fig. 5e

Ac@[Ca-NDI] MOCF dark-green block single crystals · Single Crystal

Solid-state/material absorption and band gap diagrams for Ac@[Ca-NDI] MOCF and Ca-NDI MOF.

Context: Target compared with pristine Ca-NDI MOF and acridine.
Measurement source: main p.2, article p.4445 · Results and discussion · Figs. 1b, 3a and S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Experimental optical bandgap of Ac@[Ca-NDI] MOCFMarked as a best value within this paper	1.35 eV	—	—	Text Exact Reported	main p.2, article p.4445 · Results and discussion · Fig. 1b and Fig. S8
Experimental optical bandgap of Ca-NDI MOF	2.79 eV	—	—	Text Exact Reported	main p.2, article p.4445 · Results and discussion · Fig. 1b and Fig. S8
Aqueous UV-vis absorption range of Ac@[Ca-NDI] MOCF	250-1200 nm	—	—	Text Range	main p.4, article p.4447 · Results and discussion · Fig. S16

Ac@[Ca-NDI] MOCF dark-green block single crystals · Single Crystal

Survey spectra comparing nitrogen content in Ac@[Ca-NDI] MOCF and Ca-NDI MOF.

Context: Target compared with pristine Ca-NDI MOF.
Measurement source: main p.2, article p.4445 · Results and discussion · Fig. S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Nitrogen content in Ac@[Ca-NDI] MOCF by XPS	10.01%	—	—	Text Exact Reported	main p.2, article p.4445 · Results and discussion · Fig. S5
Nitrogen content in Ca-NDI MOF by XPS	5.72%	—	—	Text Exact Reported	main p.2, article p.4445 · Results and discussion · Fig. S5