Other — Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants

4 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ac@[Ca-NDI] MOCF powder · Powder

Water contact angle measured to evaluate hydrophilicity of Ac@[Ca-NDI] MOCF.

Context: Target MOCF surface property.
Measurement source: main p.4, article p.4447 · Results and discussion · Fig. S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Static water contact angle of Ac@[Ca-NDI] MOCF	~16.2 degree	—	~	Text Approximate	main p.4, article p.4447 · Results and discussion · Fig. S20

Ac@[Ca-NDI] MOCF powder · Powder

90 mg MOCF powder in quartz cell, 808 nm laser, 0.6 W/cm2 for conversion efficiency; power density varied from 0.2 to 0.8 W/cm2.

Atmosphere: Air or ambient atmosphere not specified.
Geometry: Powder in quartz cell.
Context: Target MOCF powder; Ca-NDI MOF comparison in Fig. 3b.
Measurement source: SI pp.4-5 · Photothermal Experiments · Figs. 3b-e and S12-S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Temperature reached after 50 s under 808 nm heating	108 C within 50 s	—	—	Text Exact Reported	main p.3, article p.4446 · Results and discussion · Fig. 3b
Initial temperature under 808 nm heating	29.9 C	—	—	Text Exact Reported	main p.3, article p.4446 · Results and discussion · Fig. 3b
Photothermal conversion efficiency under 808 nm irradiationMarked as a best value within this paper	70.65%	—	—	Text Exact Reported	SI p.5 · Photothermal Experiments · Figs. S12 and S13
Maximum temperature at 0.8 W cm-2	131.1 C	—	—	Text Exact Reported	main p.3, article p.4446 · Results and discussion · Fig. 3d and Fig. S14
Maximum temperature at 0.2 W cm-2	55.9 C	—	—	Text Exact Reported	main p.3, article p.4446 · Results and discussion · Fig. 3d and Fig. S14

Ac@[Ca-NDI] MOCF powder · Powder

30 mg powder dispersed at 1 mg/mL; 300 W Xe lamp, 300 nm < lambda < 1200 nm, about 10 cm above liquid surface.

Geometry: Aqueous dispersion; infrared thermal imaging.
Context: Target MOCF in water with pure-water blank.
Measurement source: SI p.5 · Photothermal Experiments · Figs. 3f, S17 and S18

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Aqueous dispersion temperature under 300-1200 nm Xe lamp	62.1 C within 20 min	—	—	Text Exact Reported	main p.4, article p.4447 · Results and discussion · Fig. 3f and Fig. S18
Aqueous dispersion temperature under 300-780 nm Xe lamp	46.5 C within 20 min	—	—	Text Exact Reported	main p.4, article p.4447 · Results and discussion · Fig. 3f
Pure-water blank temperature under Xe lamp	51.8 C	—	—	Text Exact Reported	main p.4, article p.4447 · Results and discussion · Fig. 3f

Ac@[Ca-NDI] MOCF powder · Powder

TGA spectra of Ac@[Ca-NDI] MOCF and Ca-NDI MOF; used to assess stability near reaction temperature.

Context: Target compared with pristine Ca-NDI MOF.
Measurement source: main p.4, article p.4447 · Results and discussion · Fig. S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TGA weight loss below 100 C	only a slight weight loss below 100 C	—	—	Qualitative Qualitative	main p.4, article p.4447 · Results and discussion · Fig. S19