cMOF Evidence Base
Electrochemistry Application — Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants

Measurement evidence

Electrochemistry Application

Metal–(organic cocrystal) framework with a photothermal effect boosting the photocatalytic degradation of pollutants · Liu M., Liu K., Yan Z. et al. · Journal of Materials Chemistry A · 2026 · 4444-4452

2 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Photocatalytic methyl orange degradation

Ac@[Ca-NDI] MOCF powder · Powder

Degradation curves compared Ac@[Ca-NDI] MOCF and Ca-NDI MOF; condensation and photothermal conditions included.

Geometry
Aqueous dye degradation suspension.
Context
Target compared with pristine Ca-NDI MOF.
Measurement source
main p.6, article p.4449 · Results and discussion · Fig. 4f and Fig. S26
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Methyl orange degradation by Ac@[Ca-NDI] MOCF~63% within 100 min—~Text
Approximate		main p.6, article p.4449 · Results and discussion · Fig. 4f
Methyl orange degradation by Ca-NDI MOF~40% within 100 min—~Text
Approximate		main p.6, article p.4449 · Results and discussion · Fig. 4f
Methyl orange degradation rate constant for Ac@[Ca-NDI] MOCF with photothermal effectMarked as a best value within this paper0.01362 min-1——Text
Exact Reported		main p.6, article p.4449 · Results and discussion · Fig. S26
Methyl orange degradation rate constant for cooled Ac@[Ca-NDI] MOCF0.01071 min-1——Text
Exact Reported		main p.6, article p.4449 · Results and discussion · Fig. S26
Methyl orange degradation rate constant for Ca-NDI MOF0.00479 min-1——Text
Exact Reported		main p.6, article p.4449 · Results and discussion · Fig. S26

Photocatalytic phenol degradation monitored by 4-aminoantipyrine UV-vis assay

UV-visible and optical absorption spectroscopy

Ac@[Ca-NDI] MOCF powder · Powder

300 W Xe lamp, 300 nm < lambda < 1200 nm; phenol 30 mg/L; dark adsorption-desorption equilibrium 30 min; sampled every 20 min; absorbance at 510 nm.

Atmosphere
Ambient unless otherwise noted; separate argon control reported.
Geometry
Aqueous catalyst-pollutant suspension.
Context
Target compared with pristine Ca-NDI MOF and with/without condensation-water cooling.
Measurement source
SI p.5 · Photocatalytic Experiments · Figs. 4a-d, S21-S23
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Phenol degradation by Ac@[Ca-NDI] MOCF under full-spectrum Xe lamp46% within 120 min——Text
Exact Reported		main p.4, article p.4447 · Results and discussion · Fig. 4a
Phenol degradation by Ca-NDI MOF under full-spectrum Xe lamp18% within 120 min——Text
Exact Reported		main p.4, article p.4447 · Results and discussion · Fig. 4a
Phenol degradation by Ac@[Ca-NDI] MOCF without condensation cooling~57% in 80 min—~Text
Approximate		main p.5, article p.4448 · Results and discussion · Fig. 4c and Fig. S22
Phenol degradation rate constant for Ac@[Ca-NDI] MOCF0.00465 min-1——Text
Exact Reported		main p.4, article p.4447 · Results and discussion · Fig. 4b
Phenol degradation rate constant for Ca-NDI MOF0.00162 min-1——Text
Exact Reported		main p.4, article p.4447 · Results and discussion · Fig. 4b
Photocatalytic rate improvement of Ac@[Ca-NDI] over Ca-NDIMarked as a best value within this paper2.87-fold——Text
Exact Reported		main p.4, article p.4447 · Results and discussion · Fig. 4b
Additional rate increase from photothermal effectMarked as a best value within this paper~2.12-times—~Text
Approximate		main p.5, article p.4448 · Results and discussion · Fig. S22
Phenol degradation rate constant without condensation cooling0.00984 min-1——Text
Exact Reported		main p.5, article p.4448 · Results and discussion · Fig. S22
Phenol degradation rate constant under 300-780 nm Xe lamp0.00395 min-1——Text
Exact Reported		main p.5, article p.4448 · Results and discussion · Fig. S23