Complete recipeSource: Both
Route 1: Solvothermal
SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF
Metal precursorsCa(NO3)2, 28 mg; reagent list identifies calcium nitrate tetrahydrate Ca(NO3)2.4H2O.
Linker precursorsH4BINDI, 21 mg.
SolventsDMF, 4 mL.
AdditivesAcridine, 62.5 mg; 3 M HCl, 0.6 mL.
AtmosphereNot specified.
Temperature100
Time24
Work-upSonication 0.5 h before heating; slow cooling to room temperature to obtain dark green block crystals.
ActivationNot specified.
Scalability context15 mL pressure-resistant vial batch synthesis; excess acridine used for purity.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Ca(NO3)2 / calcium nitrate tetrahydrate (Ca(NO3)2.4H2O) | 28 mg | SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF |
| Linker | H4BINDI | 21 mg · 98% | SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF |
| Additive | acridine (C13H9N) | 62.5 mg · 98% | SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF |
| Solvent | N,N-dimethylformamide (DMF) | 4 mL · HPLC | SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF |
| Acid | hydrochloric acid (HCl) | 0.6 mL · 3 M | SI p.3 · Synthesis of Ac@[Ca-NDI] MOCF |