Spectroscopy — Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

iodine-treated Tb-MOF bulk powder · Powder

Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps determined from Tauc plots.

Context: Iodine-treated target optical gap compared with pristine Tb-MOF.
Measurement source: p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap from absorption band, iodine-treated Tb-MOFMarked as a best value within this paper	1.6 eV	1.6 eV	—	Text Rounded Reported	p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3A
Tauc-plot optical band gap, iodine-treated Tb-MOF	1.7 eV	1.7 eV	—	Text Rounded Reported	p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3B
absorption band extent of iodine-treated Tb-MOF	through ca. 760 nm	760 nm	ca.	Text Approximate	p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3A

pristine Tb-MOF bulk powder/crystals · Powder

Shimadzu UV-2600 with integrated sphere, 200-1100 nm range; optical band gaps determined from Tauc plots.

Context: Pristine-control optical gap.
Measurement source: p001 / SI page S1 · General Materials and Methods · Fig. 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap from absorption onset, pristine Tb-MOF	ca. 2 eV	2 eV	ca.	Text Approximate	p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3A
Tauc-plot optical band gap, pristine Tb-MOF	2.1 eV	2.1 eV	—	Text Rounded Reported	p003 / article page 6159 · Optical spectroscopy discussion · Fig. 3B
absorption onset of pristine Tb-MOF	618 nm	618 nm	—	Text Rounded Reported	p002 / article page 6158 · Optical spectroscopy discussion · Fig. 3A

iodine-treated Tb-MOF bulk powder · Powder

Freshly prepared and air-exposed iodine-treated powder in 4 mm quartz tube; double integration used for spin quantification.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR spin concentration in iodine-treated Tb-MOFMarked as a best value within this paper	7.7 x 10^20 spins mol^-1	770000000000000000000 spins mol^-1	—	Text Rounded Reported	p002 / article page 6158 · EPR discussion · Fig. 2

pristine Tb-MOF bulk powder/crystals · Powder

Freshly prepared and air-exposed powdered sample in 4 mm quartz tube; double integration used for spin quantification.

Temperature: room temperature
Atmosphere: air-exposed sample; measurement atmosphere not specified
Context: Pristine-control radical population.
Measurement source: p001 / SI page S1 · General Materials and Methods · Fig. 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR spin concentration in pristine Tb-MOF	1.7 x 10^19 spins mol^-1	17000000000000000000 spins mol^-1	—	Text Rounded Reported	p002 / article page 6158 · EPR discussion · Fig. 2