Other — Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Measurement evidence

Other

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand · Gordillo M.A., Benavides P.A., McMillen C. et al. · Materials Advances · 2022 · 6157-6160

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

thermogravimetric analysis (TGA)

Thermogravimetric analysis

iodine-treated Tb-MOF bulk powder · Powder

TGA under N2 atmosphere using an SDT Q600 instrument; used to check residual solvent and physisorbed iodine.

Atmosphere: N2
Context: Iodine-treated residual-solvent and iodine-retention check.
Measurement source: p002 / article page 6158 · TGA discussion · Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TGA plateau and physisorbed iodine conclusion	plateau until ca. 320 deg C; no physisorbed I2 left in iodine-treated Tb-MOF	593.15 K	ca.	Text Approximate	p002 / article page 6158 · TGA discussion · Fig. S4
weight loss before 150 deg C	ca. 9% before 150 deg C for both pristine and I2-treated Tb-MOFs	9 %	ca.	Text Approximate	p002 / article page 6158 · TGA discussion · Fig. S4

thermogravimetric analysis (TGA)

Thermogravimetric analysis

pristine Tb-MOF bulk powder/crystals · Powder

TGA under N2 atmosphere using an SDT Q600 instrument.

Atmosphere: N2
Context: Pristine residual-solvent loss comparison.
Measurement source: p001 / SI page S1 · General Materials and Methods · Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source