Spectroscopy — Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device

4 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Bulk/crude material of compound 1 · Powder

Compound 1 in sealed EPR tube under inert gas; irradiated at 360 nm with ISS P110 lamp for 1 h under argon; monitored after air exposure.

Temperature: room temperature
Atmosphere: argon during irradiation; air during recovery
Context: pristine framework under photochemical disulfide cleavage/reformation
Measurement source: 4-5 · Photoreversible Polymerization · Figure 3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EPR g value after photoirradiation	g = 2.008	—	—	Text Exact Reported	4 · Photoreversible Polymerization · Figure 3
organic radical solid-state lifetime	stable in the solid state up to 28 h	—	—	Text Rounded Reported	5 · Photoreversible Polymerization · Figure 3

Bulk/crude material of compound 1 · Powder

PerkinElmer FT-IR spectrum RX1; 4500-500 cm-1.

Context: 2-MBA precursor compared with pristine compound 1
Measurement source: 2 and 4 · Materials and Physical Method; IR, Raman Spectra, TGA, and PXRD Analysis · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
IR asymmetric carboxylate stretch	1667 cm-1	—	—	Text Exact Reported	2 · Synthesis · Figure S1
2-MBA S-H stretch	2518 cm-1	—	—	Text Exact Reported	4 · IR, Raman Spectra, TGA, and PXRD Analysis · Figure S1

Bulk/crude material of compound 1 · Powder

As-made compound 1, NaBH4-cleaved crystals after overnight dipping, and air-reformed compound 1.

Atmosphere: NaBH4 solution treatment, then air exposure for self-healing
Context: pristine framework with reversible disulfide cleavage/reformation
Measurement source: 4 · IR, Raman Spectra, TGA, and PXRD Analysis · Figure S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman S-H band after NaBH4 cleavage	2580 cm-1	—	—	Text Exact Reported	4 · IR, Raman Spectra, TGA, and PXRD Analysis · Figure S3
Raman S-S band	~510 cm-1	—	—	Text Approximate	4 · IR, Raman Spectra, TGA, and PXRD Analysis · Figure S3

Spin-coated compound 1 thin film · Thin Film

Thin film of compound 1 prepared by dispersion in DMF on glass plate; spectra in 400-800 nm range.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct optical band gap	~3.71 eV	—	—	Text Approximate	6 · Optoelectronic Studies · Figure 5