cMOF Evidence Base
Electrochemistry Application — Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device

Measurement evidence

Electrochemistry Application

Biporous Cd(II) Coordination Polymer via in Situ Disulfide Bond Formation: Self-Healing and Application to Photosensitive Optoelectronic Device · Naskar K., Dey A., Maity S. et al. · Inorganic Chemistry · 2020 · 5518-5528

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Voltammetry

Bulk/crude material of compound 1 · Powder

Glass carbon electrode with deposit of compound 1 at 296 K in CH3CN, 0.2 M [N(n-Bu)4]PF6, scan rate 100 mV/s, potential range +2.0 to -2.0 V, Fc+/Fc reference.

Temperature
296
Geometry
glassy carbon working electrode
Context
compound 1 deposit on electrode; diphenyldisulfide and 2-MBA fragment controls
Measurement source
5-6 · Electrochemical Studies · Figure 4a-c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
2-MBA control oxidation potential+0.22 V——Text
Exact Reported		6 · Electrochemical Studies · Figure 4c
compound 1 peak separationDeltaV = 190 mV——Text
Exact Reported		6 · Electrochemical Studies · Figure 4a
compound 1 cathodic peak potentialEpc = -1.23 V——Text
Exact Reported		6 · Electrochemical Studies · Figure 4a
diphenyldisulfide control cathodic potential-1.04 V——Text
Exact Reported		6 · Electrochemical Studies · Figure 4b

UV-vis spectroelectrochemistry

UV-visible and optical absorption spectroscopy

Bulk/crude material of compound 1 · Powder

Electrolysis in DMF with 0.2 M [N(n-Bu)4]PF6 during disulfide reduction.

Geometry
spectroelectrochemical cell with platinum gauze/SEC-C platinum electrodes
Context
compound 1 under electrochemical S-S/S-H transformation
Measurement source
6 · Electrochemical Studies · Figure 4d
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
new spectroelectrochemical absorption band450 nm——Text
Exact Reported		6 · Electrochemical Studies · Figure 4d