Measurement evidence
Iron-Based 2D Conductive Metal-Organic Framework Nanostructure with Enhanced Pseudocapacitance · Stodolka M., Choi J.Y., Flood J. et al. · ACS Applied Nano Materials · 2022 · 2156-2162
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Fe-HHTP powder · Powder
Bruker Elexsys E 500 with SHQE resonator; microwave power 6.325 mW, modulation amplitude 4 G, modulation frequency 100 kHz.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EPR high-spin Fe(III) G value | near G = 1620 | — | — | Text Approximate | main p.4 · Results and Discussion · Figure 5a |
| EPR organic monoradical G value | G = 3509 | — | — | Text Exact Reported | main p.4 · Results and Discussion · Figure 5a |
Fe-HHTP powder · Powder
Cary 630 ATR FT-IR; TGA under nitrogen to 600 deg C at 10 deg C min-1.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| DMF C-H formyl stretch | ~2900 cm-1 | — | — | Text Approximate | main p.2 · Results and Discussion · Figure S8a |
| DMF C=O stretch | ~1640 cm-1 | — | — | Text Approximate | main p.2 · Results and Discussion · Figure S8a |
| DMF C(=O)-N out-of-plane bending | ~700 cm-1 | — | — | Text Approximate | main p.2 · Results and Discussion · Figure S8a |
| TGA coordinated DMF loss temperature | weight loss step up to 150 deg C | 423.15 K | — | Text Rounded Reported | main p.2 · Results and Discussion · Figure S8b |
Fe-HHTP powder · Powder
CARY 5000 UV-Vis spectrophotometer; sample dispersed in isopropyl alcohol.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| strong absorption wavelength | 650 nm | — | — | Text Rounded Reported | main p.4 · Results and Discussion · Figure 4a |
| optical band gapMarked as a best value within this paper | 1.11 eV | — | — | Text Exact Reported | main p.4 · Results and Discussion · Figure 4a inset |
Fe-HHTP powder · Powder
K-alpha spectrometer with Al Kalpha X-ray source.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Fe(II) Fe 2p3/2 multiplet/satellite binding energies | 708.53, 709.73, 710.43 eV; satellite 714.98 eV | — | — | Text Exact Reported | main p.4 · Results and Discussion · Figure 5b |
| Fe(III) Fe 2p3/2 multiplet/satellite binding energies | 710.93, 711.68, 712.53, 713.53 eV; satellite 717.93 eV | — | — | Text Exact Reported | main p.4 · Results and Discussion · Figure 5b |