Spectroscopy — Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker

4 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Cd-m-TTFTB red rod-like crystals · Powder

chiMT versus T plots measured in a DC field of 1 kOe; values reported at 300 K.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cd-m-TTFTB chiMT at 300 K	0.155 cm3 K mol-1 at 300 K	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies
m-H4TTFTB chiMT at 300 K	0.098 cm3 K mol-1 at 300 K	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies

as-synthesised Cd-m-TTFTB red rod-like crystals · Powder

Room-temperature solid-state spectra with BaSO4 baseline; Kubelka-Munk transform.

Temperature: room temperature
Context: pristine Cd-m-TTFTB
Measurement source: p005 / journal page 4945 · Semiconducting Properties · Figure 5; Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cd-m-TTFTB optical band gap	approximately 1.87 eV	—	—	Text Approximate	p005 / journal page 4945 · Semiconducting Properties · Figure S13

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder

Solid-state EPR spectra of m-H4TTFTB ligand, Zn-m-TTFTB, and Cd-m-TTFTB.

Context: pristine CPs compared with molecular linker control
Measurement source: p005 / journal page 4945 · Charge Transfer Studies · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cd-m-TTFTB EPR g_x	gx = 2.0129	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
Cd-m-TTFTB EPR g_y	gy = 2.0070	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
Cd-m-TTFTB EPR g_z	gz = 2.0046	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
m-H4TTFTB EPR g_x	gx = 2.0114	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
m-H4TTFTB EPR g_y	gy = 2.0064	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
m-H4TTFTB EPR g_z	gz = 2.0039	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
Zn-m-TTFTB EPR g_x	gx = 2.0146	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
Zn-m-TTFTB EPR g_y	gy = 2.0060	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6
Zn-m-TTFTB EPR g_z	gz = 2.0028	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies · Figure 6

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder

Room-temperature solid-state spectra with BaSO4 baseline; Kubelka-Munk transform.

Temperature: room temperature
Context: pristine Zn-m-TTFTB
Measurement source: S2 and S15 · Materials and Methods · Figure 5; Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
MOF charge-transfer shoulder	small shoulder peak in the range 700-800 nm attributed to partial charge transfer of MOF samples	—	—	Text Range	p005 / journal page 4945 · Semiconducting Properties · Figure 5
Zn-m-TTFTB main absorption band	300-600 nm, assigned to n -> pi* or pi -> pi* transition of m-H4TTFTB ligand	—	—	Text Range	p005 / journal page 4945 · Semiconducting Properties · Figure 5
Zn-m-TTFTB optical band gap	approximately 1.76 eV	—	—	Text Approximate	p005 / journal page 4945 · Semiconducting Properties · Figure S13