Diffraction Structure — Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker

5 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised Cd-m-TTFTB red rod-like crystals · Powder

PXRD at room temperature; TGA at 10 C/min under N2.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cd-m-TTFTB PXRD phase agreement	experimental PXRD peak positions agree with simulated pattern	—	—	Text Qualitative	p004 / journal page 4944 · PXRD and TGA · Figure 3a
Cd-m-TTFTB thermal stability threshold	framework remained intact until 350 C	—	—	Text Rounded Reported	p004 / journal page 4944 · PXRD and TGA · Figure 3b

as-synthesised Cd-m-TTFTB red rod-like crystals · Powder

SCXRD at 296 K using Mo K alpha radiation on a Bruker D8 Venture diffractometer.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cd-m-TTFTB framework dimensionality	1D chain-like coordination polymer	—	—	Text Qualitative	p003 / journal page 4943 · Crystal Structures of Zn/Cd-m-TTFTB · Figure 2
shortest S...S distance in Cd-m-TTFTB	4.11 Angstrom	—	—	Text Rounded Reported	p003 / journal page 4943 · Crystal Structures of Zn/Cd-m-TTFTB · Figure S8
Cd-m-TTFTB space group	P21/c	—	—	Table Exact Reported	p002 / journal page 4942 · Table 1 · Table 1

m-H4TTFTB ligand control · Powder

Molecular linker single-crystal structure at 192.98 K.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
m-H4TTFTB shortest pi...pi distance	3.273 Angstrom	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies
m-H4TTFTB shortest S...S distance	3.903 Angstrom	—	—	Text Exact Reported	p005 / journal page 4945 · Charge Transfer Studies

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder

PXRD at room temperature; TGA at 10 C/min under N2.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-m-TTFTB PXRD phase agreement	experimental PXRD peak positions agree with simulated pattern	—	—	Text Qualitative	p004 / journal page 4944 · PXRD and TGA · Figure 3a
Zn-m-TTFTB thermal stability threshold	framework remained intact until 350 C	—	—	Text Rounded Reported	p004 / journal page 4944 · PXRD and TGA · Figure 3b

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder

SCXRD at 100 K; data collected at Shanghai Synchrotron Radiation Facility.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn-m-TTFTB framework dimensionality	2D coordination polymer; threefold interpenetrated nonporous 2D structure with hydrogen-bonded 3D assembly	—	—	Text Qualitative	p003 / journal page 4943 · Crystal Structures of Zn/Cd-m-TTFTB · Figure 1
shortest S...S distance in Zn-m-TTFTB	3.95 Angstrom	—	—	Text Rounded Reported	p003 / journal page 4943 · Crystal Structures of Zn/Cd-m-TTFTB · Figure S3
Zn-m-TTFTB space group	P21/c	—	—	Table Exact Reported	p002 / journal page 4942 · Table 1 · Table 1