cMOF Evidence Base
Electrochemistry Application — Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker

Measurement evidence

Electrochemistry Application

Crystal Structure and Electrochemical and Charge Transfer Properties in Redox-Active Coordination Polymers Based on a Truncated Tetrathiafulvalene Linker · Yang Z.-M., Li Y.-Y., Zhou X.-C. et al. · Crystal Growth and Design · 2022 · 4941-4947

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state cyclic voltammetry

Voltammetry

as-synthesised Cd-m-TTFTB red rod-like crystals · Powder

Powder paste on glassy carbon working electrode; 0.1 M LiBF4 in CH3CN/MeCN; scan rate 100 mV/s; potentials versus Fc/Fc+.

Atmosphere
argon-bubbled electrolyte
Geometry
1.5 mm diameter glassy carbon working electrode, Pt wire auxiliary electrode, Ag wire quasi-reference electrode
Context
pristine Cd-m-TTFTB powder paste
Measurement source
S2 and S14 · Materials and Methods · Figure 4; Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cd-m-TTFTB first oxidation process0.12 V vs Fc/Fc+——Text
Exact Reported		p004 / journal page 4944 · Cyclic Voltammetry · Figure 4
Cd-m-TTFTB second oxidation process0.44 V vs Fc/Fc+——Text
Exact Reported		p004 / journal page 4944 · Cyclic Voltammetry · Figure 4

solid-state cyclic voltammetry

Voltammetry

as-synthesised Zn-m-TTFTB red rod-like crystals · Powder

Powder paste on glassy carbon working electrode; 0.1 M LiBF4 in CH3CN/MeCN; scan rate 100 mV/s; potentials versus Fc/Fc+.

Atmosphere
argon-bubbled electrolyte
Geometry
1.5 mm diameter glassy carbon working electrode, Pt wire auxiliary electrode, Ag wire quasi-reference electrode
Context
pristine Zn-m-TTFTB powder paste
Measurement source
p004 / journal page 4944 · Cyclic Voltammetry · Figure 4; Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
scan-rate effect on CV featuresfaster sweep rates resulted in broad features due to slow diffusion kinetics——Text
Qualitative		p005 / journal page 4945 · Cyclic Voltammetry · Figures S11-S12
Zn-m-TTFTB first oxidation process0.08 V vs Fc/Fc+——Text
Exact Reported		p004 / journal page 4944 · Cyclic Voltammetry · Figure 4
Zn-m-TTFTB second oxidation process0.43 V vs Fc/Fc+——Text
Exact Reported		p004 / journal page 4944 · Cyclic Voltammetry · Figure 4