Spectroscopy — Naphthalene Diimide-Based Hydrogen-Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applications

4 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

ammonia-doped NDI(CPOH)2-SC sensor device · Single Crystal

ammonia-doped NDI(CPOH)2-SC compared with TEMPO

Atmosphere: ammonia-doped
Context: ammonia-doped HOF
Measurement source: p.7 · 2.5. The Potential Application of NDI(CPOH)2 SC-Based HOF Systems as a Sensor · Figure S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ammonia-doped ESR peak intensity area	2.79 x 10^7 mmol^-1	—	—	Caption Exact Reported	Figure S19 caption · Figure S19
ammonia-doped radical ratio relative to TEMPO	1.04%	—	—	Text Rounded Reported	p.7 · 2.5. The Potential Application of NDI(CPOH)2 SC-Based HOF Systems as a Sensor · Figure S19

Device C vacuum-pretreated hydrazine-doped NDI(CPOH)2-SC · Single Crystal

comparison of pristine, hydrazine-doped normal and hydrazine-doped vacuum-treated samples

Context: hydrazine-doped HOF radical amount
Measurement source: p.5 · 2.3. Electronic Characterization of NDI(CPOH)2-Based HOF · Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Device B radical amount	ca. 19.7% (-0.2e per molecule)	-0.2 e per molecule	ca.	Text Approximate	p.5 · 2.3. Electronic Characterization of NDI(CPOH)2-Based HOF · Figure S12
Device C radical amountMarked as a best value within this paper	53.5% (-0.5e per molecule)	-0.5 e per molecule	—	Text Rounded Reported	p.5 · 2.3. Electronic Characterization of NDI(CPOH)2-Based HOF · Figure S12
Device B hydrazine-doped normal ESR peak intensity area	4.80 x 10^8 mmol^-1	—	—	Caption Exact Reported	p.13 · Figure S12 caption · Figure S12
Device C hydrazine-doped vacuum ESR peak intensity area	1.3 x 10^8 mmol^-1	—	—	Caption Exact Reported	p.13 · Figure S12 caption · Figure S12
ESR peak intensity area, pristine	2.44 x 10^9 mmol^-1	—	—	Caption Exact Reported	Figure S12 caption · Figure S12

Device B hydrazine-doped NDI(CPOH)2-SC, normal treatment · Single Crystal

comparison of pristine and hydrazine-doped NDI(CPOH)2-SCs; TEMPO used as ESR reference

Context: hydrazine-doped HOF versus pristine HOF
Measurement source: p.3 · 2.2. Confirmation of Effective Hydrazine Doping into NDI(CPOH)2-Based HOF · Figures 1f, S7-S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
hydrazine-doped electron affinity	-3.7 eV	—	—	Text Rounded Reported	Figure S8 caption · Figure S8
hydrazine-doped ionisation potential	-5.5 eV	—	—	Text Rounded Reported	Figure S7 caption · Figure S7
pristine HOMO / PES onset	-6.3 eV	—	—	Text Rounded Reported	p.3 · 2.2. Confirmation of Effective Hydrazine Doping into NDI(CPOH)2-Based HOF · Figure 1f; Figure S7
pristine LUMO / LEIPS level	-4.0 eV	—	—	Text Rounded Reported	Figure S8 caption · Figure S8
hydrazine-doped NDI radical absorption bands	new bands between 450 and 700 nm and in the infrared region	—	—	Text Qualitative	p.3 · 2.2. Confirmation of Effective Hydrazine Doping into NDI(CPOH)2-Based HOF · Figure S10

Device A pristine drop-cast NDI(CPOH)2-SC · Single Crystal

grown non-doped single crystals dissolved in deuterated chloroform; NDI:DMF guest ratio from peak integrals

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NDI:DMF ratio by NMR	1:0.4	—	—	Text Rounded Reported	p.3 · 2.1. Preparation of Pristine NDI(CPOH)2-Based HOF · Figure S4