Spectroscopy — Cation dependent charge transport in linear dicarboxylate based isotypical 1D coordination polymers

4 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

powdered compound 1 · Powder

4500-500 cm-1 range.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
asymmetric carboxylate stretch	1592 cm-1	—	—	Text Exact Reported	2 · Synthesis of compounds 1 and 2 · Fig. S6
symmetric carboxylate stretch	1317 cm-1	—	—	Text Exact Reported	2 · Synthesis of compounds 1 and 2 · Fig. S6

powdered compound 2 · Powder

4500-500 cm-1 range.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
asymmetric carboxylate stretch	1590 cm-1	—	—	Text Exact Reported	2 · Synthesis of compounds 1 and 2 · Fig. S7
symmetric carboxylate stretch	1322 cm-1	—	—	Text Exact Reported	2 · Synthesis of compounds 1 and 2 · Fig. S7

powdered compound 1 · Powder

Shimadzu 2401 PC UV-vis spectrophotometer, 250-800 nm; direct optical band gap from (alpha h nu)^2 versus h nu.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct optical band gapMarked as a best value within this paper	3.51 eV	—	—	Text Rounded Reported	4 · Optical characterization · Fig. 3

powdered compound 2 · Powder

Shimadzu 2401 PC UV-vis spectrophotometer, 250-800 nm; direct optical band gap from (alpha h nu)^2 versus h nu.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct optical band gap	4.21 eV	—	—	Text Rounded Reported	4 · Optical characterization · Fig. 3