Measurement evidence
Decoupling Redox Hopping and Catalysis in Metal-Organic Frameworks -based Electrocatalytic CO2 Reduction · Li X., Surendran Rajasree S., Gude V. et al. · Angewandte Chemie - International Edition · 2023 · e202219046
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
CoPc@NU-1000-h · Powder
Powder samples mixed with KBr and measured under dry air purge
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| OH/H2O stretching peak for anchored catalystsMarked as a best value within this paper | about 3676 cm-1 | — | — | Text Rounded Reported | 2 · Results and Discussion · Figure 2a |
| broad OH band for unmodified NU-1000 | 3637 cm-1 | — | — | Text Exact Reported | 3 · Results and Discussion · Figure 2a |
CoPc@NU-1000-h · Powder
ca 2 mg MOF digested in 1 M KOH for 10 min, neutralised with 1 M HCl, diluted in DMF to 5 mL
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| CoPc loading per SBU in CoPc@NU-1000-hMarked as a best value within this paper | 0.58 CoPc per SBU | — | — | Caption Exact Reported | 8 · Structural characterizations · Figure S6 |
| CoPc loading per SBU in CoPc@NU-1000-l | 0.25 CoPc per SBU | — | — | Caption Exact Reported | 8 · Structural characterizations · Figure S6 |
| TPP(Co) loading per SBU in TPP(Co)@NU-1000 | 0.50 TPP(Co) per SBU | — | — | Caption Exact Reported | 8 · Structural characterizations · Figure S6 |
CoPc@NU-1000-h · Powder
Co 2p binding energies measured on Kratos Axis Ultra DLD with monochromatic Al K radiation source
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Co 2p1/2 binding energy | 796.2 eV | — | — | Text Exact Reported | 3 · Results and Discussion · Figure S5 |
| Co 2p3/2 binding energy | 781.4 eV | — | — | Text Exact Reported | 3 · Results and Discussion · Figure S5 |