Spectroscopy — Electrically regulating nonlinear optical limiting of metal-organic framework film

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-HHTP[001] film · Thin Film

IRRAS with Bruker Vertex 70 FTIR, 2 cm-1 resolution, 80 deg incidence; XPS with ESCALAB250Xi; Raman spectra in SI.

Geometry: film and powder samples
Context: Pristine Cu-HHTP powder and films compared with HHTP ligand.
Measurement source: 3, 7 · Characterization; Materials and instrumentation · Supplementary Figs. 3-6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-O stretching vibration shift after Cu-HHTP formation	1217 to 1206 cm-1	—	—	Text Rounded Reported	3 · Characterization · Supplementary Fig. 3
Raman OH and C=O peaks disappear after Cu coordination	OH peaks at 2881, 3054, 3197 cm-1 and C=O at 1620 cm-1 almost disappeared	—	—	Text Qualitative	3 · Characterization · Supplementary Fig. 4

Cu-HHTP[001] film · Thin Film

UV-vis spectra measured by Lambda 365; band gaps estimated from Tauc plots.

Geometry: solid-state thin-film UV-vis
Context: Pristine oriented Cu-HHTP films.
Measurement source: 3-4, 7 · Characterization; Materials and instrumentation · Fig. 3c,d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-HHTP[001] band gap	1.53 eV	—	—	Text Rounded Reported	3 · Characterization · Fig. 3d
Cu-HHTP[100] band gap	1.32 eV	—	—	Text Rounded Reported	3 · Characterization · Fig. 3d
Cu-HHTP[001] UV-vis absorption peaks	269, 356 and 637 nm	—	—	Text Rounded Reported	3 · Characterization · Fig. 3c
Cu-HHTP[100] UV-vis absorption peaks	270, 363 and 644 nm	—	—	Text Rounded Reported	3 · Characterization · Fig. 3c