Porosity — Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP

3 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Co-HHTP powder · Powder

Co-HHTP immersed in cationic MB+ and anionic MO- dye solutions for 0.5 h; same-concentration MB comparison with Ni-HHTP and HHTP is partly SI-only.

Atmosphere: solution, not specified
Geometry: powder adsorption test
Context: pristine Co-HHTP pore/charge probe
Measurement source: 4-5 · 3.2 ECL Performance · Figure 3E-F; Figure S3 cited

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Methylene blue removal by Co-HHTP after 0.5 hMarked as a best value within this paper	complete MB+ removal at 0.5 h	—	complete interpreted as 100%	Text Approximate	5 · 3.2 ECL Performance · Figure 3E; Figure S3
Methylene blue removal by Ni-HHTP after 0.5 h	16.8% MB+ removal	—	—	Text Exact Reported	5 · 3.2 ECL Performance · Figure S3A-D cited
Methyl orange adsorption by Co-HHTP	minimal adsorption of MO- after 0.5 h	—	—	Text Qualitative	5 · 3.2 ECL Performance · Figure 3F

Co-HHTP powder · Powder

3 mg powder in 4 mL of 0.1 mmol L^-1 methylene blue or methyl orange aqueous solution; stirred at room temperature for up to 24 h.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Powder mass for dye adsorption	3 mg powder sample	—	—	Text Exact Reported	S2 · Dye adsorption experiments
Dye adsorption solution concentration	0.1 mmol L^-1	—	—	Text Exact Reported	S2 · Dye adsorption experiments
Dye adsorption stirring time	24 hours	—	—	Text Exact Reported	S2 · Dye adsorption experiments

Co-HHTP powder · Powder

Rendered SI molecular models for Co-HHTP, Ni-HHTP and luminol.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-HHTP model pore sizeMarked as a best value within this paper	16 A	—	—	Figure Axis Rounded Reported	S8 · Supporting Information · Figure S6
Luminol model X dimension	X: 4.51 A	—	—	Figure Axis Rounded Reported	S8 · Supporting Information · Figure S6
Luminol model Y dimension	Y: 8.44 A	—	—	Figure Axis Rounded Reported	S8 · Supporting Information · Figure S6
Luminol model Z dimension	Z: 8.80 A	—	—	Figure Axis Rounded Reported	S8 · Supporting Information · Figure S6
Ni-HHTP model pore size	12 A	—	—	Figure Axis Rounded Reported	S8 · Supporting Information · Figure S6