Synthesis · Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP

9 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Drop Cast

3 · 2.4. Electrochemical and ECL Measurements

Metal precursors1 mg catalyst (Co-HHTP, Ni-HHTP, HHTP, or guest-loaded analogue depending on electrode)

Linker precursorsframework already synthesised

Solvents200 uL water + 50 uL anhydrous ethanol

Additives10 uL Nafion

Atmospherenot specified

Temperatureroom temperature

Timesonicated for 40 min

Substrate orientationglassy carbon electrode, diameter 5 mm

Oxidant / reductantnone reported

Work-up5 uL suspension dropped onto glassy carbon electrode; drying details not stated

Activationnone reported

Scalability contextAnalytical electrode preparation; not a scalable film synthesis route.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	catalyst	1 mg	3 · 2.4. Electrochemical and ECL Measurements
Solvent	water	200 uL	3 · 2.4. Electrochemical and ECL Measurements
Solvent	anhydrous ethanol	50 uL	3 · 2.4. Electrochemical and ECL Measurements
Additive	Nafion	10 uL	3 · 2.4. Electrochemical and ECL Measurements

Complete recipeSource: Main

Route 2: Drop Cast

3 · 2.4. Electrochemical and ECL Measurements

Metal precursors1 mg catalyst (HHTP)

Linker precursorsframework already synthesised

Solvents200 uL water + 50 uL anhydrous ethanol

Additives10 uL Nafion

Atmospherenot specified

Temperatureroom temperature

Timesonicated for 40 min

Substrate orientationglassy carbon electrode, diameter 5 mm

Oxidant / reductantnone reported

Work-up5 uL suspension dropped onto glassy carbon electrode; drying details not stated

Activationnone reported

Scalability contextAnalytical electrode preparation; not a scalable film synthesis route.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	HHTP catalyst	1 mg	3 · 2.4. Electrochemical and ECL Measurements
Solvent	water	200 uL	3 · 2.4. Electrochemical and ECL Measurements
Solvent	anhydrous ethanol	50 uL	3 · 2.4. Electrochemical and ECL Measurements
Additive	Nafion	10 uL	3 · 2.4. Electrochemical and ECL Measurements

Complete recipeSource: Main

Route 3: Drop Cast

3 · 2.4. Electrochemical and ECL Measurements

Metal precursors1 mg catalyst (luminol@Co-HHTP)

Linker precursorsframework already synthesised

Solvents200 uL water + 50 uL anhydrous ethanol

Additives10 uL Nafion

Atmospherenot specified

Temperatureroom temperature

Timesonicated for 40 min

Substrate orientationglassy carbon electrode, diameter 5 mm

Oxidant / reductantnone reported

Work-up5 uL suspension dropped onto glassy carbon electrode; drying details not stated

Activationnone reported

Scalability contextAnalytical electrode preparation; not a scalable film synthesis route.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	luminol@Co-HHTP catalyst	1 mg	3 · 2.4. Electrochemical and ECL Measurements
Solvent	water	200 uL	3 · 2.4. Electrochemical and ECL Measurements
Solvent	anhydrous ethanol	50 uL	3 · 2.4. Electrochemical and ECL Measurements
Additive	Nafion	10 uL	3 · 2.4. Electrochemical and ECL Measurements

Complete recipeSource: Main

Route 4: Other

3 · 2.2. Synthesis of Luminol@M-HHTP

Metal precursorsprepared Co-HHTP sample, 30 mg

Linker precursorsframework already present in Co-HHTP; luminol guest 0.010 g

Solvents9 mL deionized water + 9 mL methanol

Additivesnone reported

Atmosphereambient/not specified

Temperatureroom temperature

Time12

Oxidant / reductantnone reported

Work-upcollected by centrifugation, washed three times with methanol, dried at room temperature

Activationno separate activation reported

Scalability context30 mg MOF batch for guest loading; no yield or loading amount quantified.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	luminol	0.010 g	3 · 2.2. Synthesis of Luminol@M-HHTP
Other	prepared Co-HHTP sample	30 mg	3 · 2.2. Synthesis of Luminol@M-HHTP
Solvent	deionized water	9 mL	3 · 2.2. Synthesis of Luminol@M-HHTP
Solvent	methanol	9 mL	3 · 2.2. Synthesis of Luminol@M-HHTP

Complete recipeSource: Main

Route 5: Other

3 · 2.2. Synthesis of Luminol@M-HHTP

Metal precursorsprepared Ni-HHTP sample, 30 mg

Linker precursorsframework already present in Ni-HHTP; luminol guest 0.010 g

Solvents9 mL deionized water + 9 mL methanol

Additivesnone reported

Atmosphereambient/not specified

Temperatureroom temperature

Time12

Oxidant / reductantnone reported

Work-upcollected by centrifugation, washed three times with methanol, dried at room temperature

Activationno separate activation reported

Scalability context30 mg MOF batch for guest loading; no yield or loading amount quantified.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	luminol	0.010 g	3 · 2.2. Synthesis of Luminol@M-HHTP
Other	prepared Ni-HHTP sample	30 mg	3 · 2.2. Synthesis of Luminol@M-HHTP
Solvent	deionized water	9 mL	3 · 2.2. Synthesis of Luminol@M-HHTP
Solvent	methanol	9 mL	3 · 2.2. Synthesis of Luminol@M-HHTP

Complete recipeSource: Main

Route 6: Drop Cast

3 · 2.4. Electrochemical and ECL Measurements

Metal precursors1 mg catalyst (luminol@Ni-HHTP)

Linker precursorsframework already synthesised

Solvents200 uL water + 50 uL anhydrous ethanol

Additives10 uL Nafion

Atmospherenot specified

Temperatureroom temperature

Timesonicated for 40 min

Substrate orientationglassy carbon electrode, diameter 5 mm

Oxidant / reductantnone reported

Work-up5 uL suspension dropped onto glassy carbon electrode; drying details not stated

Activationnone reported

Scalability contextAnalytical electrode preparation; not a scalable film synthesis route.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	luminol@Ni-HHTP catalyst	1 mg	3 · 2.4. Electrochemical and ECL Measurements
Solvent	water	200 uL	3 · 2.4. Electrochemical and ECL Measurements
Solvent	anhydrous ethanol	50 uL	3 · 2.4. Electrochemical and ECL Measurements
Additive	Nafion	10 uL	3 · 2.4. Electrochemical and ECL Measurements

Complete recipeSource: Main

Route 7: Hydrothermal

3 · 2.1. Synthesis of M-HHTP

Metal precursors0.1 g M(OAc)2; M = Co for Co-HHTP, Ni for Ni-HHTP

Linker precursors0.07 g 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)

Solvents40 mL deionized water

Additivesnone reported

Atmospherenot specified; sealed 50 mL reaction vessel

Temperature85

Time12

Oxidant / reductantnone reported

Work-upcooled to room temperature, centrifuged, washed several times with deionized water and acetone, dried at room temperature

Activationno separate activation reported

Scalability context50 mL reaction vessel; no yield or scale-up discussion reported.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	M(OAc)2 (M = Co or Ni)	0.1 g	3 · 2.1. Synthesis of M-HHTP
Linker	2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)	0.07 g	3 · 2.1. Synthesis of M-HHTP
Solvent	deionized water	40 mL	3 · 2.1. Synthesis of M-HHTP

Complete recipeSource: Main

Route 8: Hydrothermal

3 · 2.1. Synthesis of M-HHTP

Metal precursors0.1 g Ni(OAc)2

Linker precursors0.07 g 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)

Solvents40 mL deionized water

Additivesnone reported

Atmospherenot specified; sealed 50 mL reaction vessel

Temperature85

Time12

Oxidant / reductantnone reported

Work-upcooled to room temperature, centrifuged, washed several times with deionized water and acetone, dried at room temperature

Activationno separate activation reported

Scalability contextNo yield or scale-up discussion reported.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(OAc)2	0.1 g	3 · 2.1. Synthesis of M-HHTP
Linker	2,3,6,7,10,11-hexahydroxytriphenylene (HHTP)	0.07 g	3 · 2.1. Synthesis of M-HHTP
Solvent	deionized water	40 mL	3 · 2.1. Synthesis of M-HHTP

Complete recipeSource: Main

Route 9: Drop Cast

3 · 2.4. Electrochemical and ECL Measurements

Metal precursors1 mg catalyst (Ni-HHTP)

Linker precursorsframework already synthesised

Solvents200 uL water + 50 uL anhydrous ethanol

Additives10 uL Nafion

Atmospherenot specified

Temperatureroom temperature

Timesonicated for 40 min

Substrate orientationglassy carbon electrode, diameter 5 mm

Oxidant / reductantnone reported

Work-up5 uL suspension dropped onto glassy carbon electrode; drying details not stated

Activationnone reported

Scalability contextAnalytical electrode preparation; not a scalable film synthesis route.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni-HHTP catalyst	1 mg	3 · 2.4. Electrochemical and ECL Measurements
Solvent	water	200 uL	3 · 2.4. Electrochemical and ECL Measurements
Solvent	anhydrous ethanol	50 uL	3 · 2.4. Electrochemical and ECL Measurements
Additive	Nafion	10 uL	3 · 2.4. Electrochemical and ECL Measurements