Measurement evidence
Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP · Liu M., Wei J., Lin S.-J. et al. · ACS Applied Electronic Materials · 2024 · 2375-2382
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Co-HHTP powder · Powder
Spectrum GX FTIR spectroscopy system; conditions otherwise not reported.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTIR adsorbed-water vibration | 1627 cm-1 | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1F |
| FTIR Co-O bond peak | 685 cm-1 | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1F |
| FTIR O-H stretch | 3372 cm-1 | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1F |
Ni-HHTP powder · Powder
Ni-HHTP powder; SI Figure S1B.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni-HHTP FTIR spectrum | FT-IR spectrum recorded for Ni-HHTP | — | — | Caption Qualitative | S3 · Supporting Information · Figure S1B |
Co-HHTP powder · Powder
Luminol fluorescence monitored versus adsorption time on Co-HHTP.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Luminol fluorescence after 12 h adsorption on Co-HHTPMarked as a best value within this paper | almost imperceptible | — | — | Text Qualitative | 5 · 3.2 ECL Performance · Figure 3G |
| luminol@Co-HHTP UV-vis luminol peak | 218 nm | — | — | Text Exact Reported | 5 · 3.2 ECL Performance · Figure S8 cited |
| luminol@Co-HHTP UV-vis luminol peak | 295 nm | — | — | Text Exact Reported | 5 · 3.2 ECL Performance · Figure S8 cited |
| luminol@Co-HHTP UV-vis luminol peak | 357 nm | — | — | Text Exact Reported | 5 · 3.2 ECL Performance · Figure S8 cited |
| Luminol molecular diameter | ~0.88 nm | — | — | Text Approximate | 5 · 3.2 ECL Performance · Figure S6 cited |
luminol@Co-HHTP powder · Powder
UV-vis patterns for luminol, luminol@Co-HHTP, Co-HHTP, luminol@Ni-HHTP and Ni-HHTP.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| luminol@Ni-HHTP UV-vis luminol peak | 220 nm | — | — | Figure Axis Rounded Reported | S10 · Supporting Information · Figure S8B |
| luminol@Ni-HHTP UV-vis luminol peak | 295 nm | — | — | Figure Axis Rounded Reported | S10 · Supporting Information · Figure S8B |
| luminol@Ni-HHTP UV-vis luminol peak | 360 nm | — | — | Figure Axis Rounded Reported | S10 · Supporting Information · Figure S8B |
Co-HHTP powder · Powder
Thermo Scientific K-Alpha with monochromatic Al Kalpha under vacuum; C 1s corrected to 284.8 eV.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| C 1s C=O binding energy | 288.50 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1J |
| C 1s C-C/C=C binding energy | 284.70 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1J |
| C 1s C-O binding energy | 286.20 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1J |
| Co 2p1/2 XPS binding energy | 797.32 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1H |
| Co 2p3/2 XPS binding energy | 781.46 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1H |
| Co 2p satellite binding energy | 785.40 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1H |
| Co 2p satellite binding energy | 802.30 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1H |
| O 1s C-O binding energy | 533.2 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1I |
| O 1s Co-O binding energy | 531.70 eV | — | — | Text Exact Reported | 4 · 3.1 Physical Characterization · Figure 1I |
| O 1s adsorbed-water binding energy | 535 eV | — | — | Text Rounded Reported | 4 · 3.1 Physical Characterization · Figure 1I |
luminol@Co-HHTP powder · Powder
Luminol@Co-HHTP compared with Co-HHTP.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| luminol@Co-HHTP XPS survey elements | Co, O, C and N elements present | — | — | Text Qualitative | 5 · 3.2 ECL Performance · Figure S9A,B |
| Co 2p1/2 binding-energy shift after luminol loading | negative shift about 0.22 eV | — | — | Figure Axis Approximate | S11 · Supporting Information · Figure S9B |
| Co 2p3/2 binding-energy shift after luminol loading | negative shift about 0.18 eV | — | — | Figure Axis Approximate | S11 · Supporting Information · Figure S9B |
luminol@Ni-HHTP powder · Powder
Luminol@Ni-HHTP compared with Ni-HHTP.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni 2p1/2 binding-energy shift after luminol loading | negative shift about 0.42 eV | — | — | Figure Axis Approximate | S11 · Supporting Information · Figure S9C |
| Ni 2p3/2 binding-energy shift after luminol loading | negative shift about 0.10 eV | — | — | Figure Axis Approximate | S11 · Supporting Information · Figure S9C |