cMOF Evidence Base
Electrical Transport — Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP

Measurement evidence

Electrical Transport

Triggering Anodic Luminol Electrochemiluminescence through Electrostatic Interactions: An Innovative Approach Utilizing Conductive Metal-Organic Framework Co-HHTP · Liu M., Wei J., Lin S.-J. et al. · ACS Applied Electronic Materials · 2024 · 2375-2382

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Co-HHTP-modified glassy carbon electrode · Electrode

Three-electrode system in 0.04 M B-R buffer; catalyst-modified GCE working electrode; 5 mV amplitude, 0.1 Hz-100 kHz.

Atmosphere
not specified; air-saturated conditions used for related CV/ECL comparison
Geometry
5 mm glassy carbon working electrode with drop-cast catalyst film
Context
pristine MOF catalyst films compared on electrode
Measurement source
3-4 · 2.4 Electrochemical and ECL Measurements; Figure 3 · Figure 3B
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co-HHTP apparent charge-transfer resistanceMarked as a best value within this paper~270 ohm semicircle diameter from Figure 3B—visual estimate +/-40 ohmFigure Axis
Approximate		4 · Figure 3 · Figure 3B
HHTP apparent charge-transfer resistance~600 ohm semicircle diameter from Figure 3B—visual estimate +/-60 ohmFigure Axis
Approximate		4 · Figure 3 · Figure 3B
Ni-HHTP apparent charge-transfer resistance~420 ohm semicircle diameter from Figure 3B—visual estimate +/-50 ohmFigure Axis
Approximate		4 · Figure 3 · Figure 3B

electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

luminol@Co-HHTP-modified glassy carbon electrode · Electrode

EIS comparison of HHTP, luminol@Ni-HHTP, and luminol@Co-HHTP modified electrodes; 5 mV, 0.1 Hz-100 kHz according to general methods.

Atmosphere
not specified
Geometry
guest-loaded catalyst film on glassy carbon electrode
Context
guest-loaded application samples compared with HHTP control
Measurement source
4-5 · Figure caption; 3.2 ECL Performance · Figure 3I
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
luminol@Co-HHTP apparent charge-transfer resistanceMarked as a best value within this paper~280 ohm semicircle diameter from Figure 3I—visual estimate +/-40 ohmFigure Axis
Approximate		4 · Figure 3 · Figure 3I
luminol@Ni-HHTP apparent charge-transfer resistance~450 ohm semicircle diameter from Figure 3I—visual estimate +/-50 ohmFigure Axis
Approximate		4 · Figure 3 · Figure 3I