Electrochemistry Application — A simplistic approach for the synthesis of Covalent Organic Frameworks(COFs) comprising of tetrafunctionalized porphyrin and polyoxometalates to uncover catalytic applications

5 measurement groups · 42 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

P@Cu-AndCOF bulk solid · Powder

DMF/CH3CN (v/v = 1:1) solution; Ag/AgCl reference electrode; Fc+/Fc internal standard.

Geometry: Solution CV.
Context: Pristine framework in solution/dispersed electrochemical test.
Measurement source: main p.5-6 · 3. Results and discussion · Figure 3; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(III)/Cu(IV) oxidation potential	0.30 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Cu(III)/Cu(II) reduction potential	-0.49 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox1	0.02 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox2	0.12 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox3	1.00 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered1	-0.92 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered2	-0.19 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Mo(VI)/Mo(V) reduction potential	-0.4 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
HOMO energy	-6.27 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4
LUMO energy	-3.44 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4

P@Cu-AndCOF bulk solid · Powder

Methylene blue and Rhodamine-B aqueous dye solutions, 50 mg/L dye and 0.1 mg/L catalyst, under 3 W LED lamp; absorbance monitored by UV-vis.

Geometry: Suspended powder catalyst in dye solution.
Context: Pristine bulk COF catalyst.
Measurement source: main p.8-11 · 3.1-3.2 Photodegradation application · Figures 8-10; Tables S8-S9 and Figures S4-S5 referenced

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
maximum UV absorption C0 for MB	1.08 a.u.	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8
MB degradation with AO scavenger	about 3%	—	—	Text Approximate	main p.10 · 3.1 Photodegradation application · Figure 9a
Rh-B degradation with AO scavenger	about 25%	—	—	Text Approximate	main p.10 · 3.1 Photodegradation application · Figure 9c
MB degradation with ISOP scavenger	about 11%	—	—	Text Approximate	main p.10-11 · 3.1 Photodegradation application · Figure 10a
Rh-B degradation with ISOP scavenger	about 14%	—	—	Text Approximate	main p.10-11 · 3.1 Photodegradation application · Figure 10c
Methylene blue degradation efficiency after 660 minMarked as a best value within this paper	89%	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8; Tables S8-S9
Rhodamine-B degradation efficiency after 660 minMarked as a best value within this paper	83%	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8; Tables S8-S9
maximum UV absorption C0 for Rh-B	0.73 a.u.	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8

P@Ni-AndCOF bulk solid · Powder

DMF/CH3CN (v/v = 1:1) solution; Ag/AgCl reference electrode; Fc+/Fc internal standard.

Geometry: Solution CV.
Context: Pristine framework in solution/dispersed electrochemical test.
Measurement source: main p.5-6 · 3. Results and discussion · Figure 3; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Eox1	0.14 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox2	1.06 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered1	-0.2 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered2	0.09 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Mo(VI)/Mo(V) reduction potential	-0.4 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ni(III)/Ni(IV) oxidation potential	0.59 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ni(III)/Ni(II) reduction potential	-0.6 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
HOMO energy	-6.98 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4
LUMO energy	-4.16 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4

P@Ni-AndCOF bulk solid · Powder

Methylene blue and Rhodamine-B aqueous dye solutions, 50 mg/L dye and 0.1 mg/L catalyst, under 3 W LED lamp; absorbance monitored by UV-vis.

Geometry: Suspended powder catalyst in dye solution.
Context: Pristine bulk COF catalyst.
Measurement source: main p.8-11 · 3.1-3.2 Photodegradation application · Figures 8-10; Tables S8-S9 and Figures S4-S5 referenced

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first-order kinetic fit R2 threshold	R2 > 0.95	—	—	Text Approximate	main p.10 · 3.2 Reaction kinetics · Figures S4-S5 referenced
MB degradation with AO scavenger	about 1%	—	—	Text Approximate	main p.10 · 3.1 Photodegradation application · Figure 9b
Rh-B degradation with AO scavenger	about 5%	—	—	Text Approximate	main p.10 · 3.1 Photodegradation application · Figure 9d
MB degradation with ISOP scavenger	about 3%	—	—	Text Approximate	main p.10-11 · 3.1 Photodegradation application · Figure 10b
Rh-B degradation with ISOP scavenger	about 26%	—	—	Text Approximate	main p.10-11 · 3.1 Photodegradation application · Figure 10d
Methylene blue degradation efficiency after 660 min	79.3%	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8; Tables S8-S9
Rhodamine-B degradation efficiency after 660 min	71.3%	—	—	Text Exact Reported	main p.9 · 3.1 Photodegradation application · Figure 8; Tables S8-S9

Tris@ZnP solution/control sample · Unknown

CV in DMF/CH3CN (v/v = 1:1) using Ag/AgCl reference and Fc+/Fc internal standard; UV-vis in DMSO.

Geometry: Solution CV.
Context: Molecular precursor/control.
Measurement source: main p.5-7 · 3. Results and discussion · Figures 2-4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Eox1	0.79 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox2	0.99 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Eox3	1.32 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered1	-1.14 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
Ered2	0.86 V	—	—	Table Exact Reported	main p.6 · 3. Results and discussion · Table 1
HOMO energy	-6.12 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4
LUMO energy	-3.3 eV	—	—	SI Table Exact Reported	SI p.7 · Table S4 · Table S4
solution optical band gap	2.82 eV	—	—	Text Exact Reported	main p.7 · 3. Results and discussion · Figure 4