cMOF Evidence Base
Other — Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks

Measurement evidence

Other

Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks · Chen G., Li Z., Huang Z. et al. · ACS Nano · 2023 · 9611-9621

9 measurement groups · 54 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Co-CoOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Co-CoOAPc119 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Co-CoOAPc-- (not reported / not determined)——SI Table
Qualitative		S31 · Table S5 · Table S5
Optical energy gap, Co-CoOAPc0.95 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Co-CoOAPc-4.01 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Co-CoOAPc-4.96 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Co-CuOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Co-CuOAPcMarked as a best value within this paper548 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Co-CuOAPc8.4 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
Qualitative MOF formation completion time, Co-CuOAPc~30 min——Text
Approximate		9614 · Results / Qualitative Comparison of M1-CuOAPc Formation Rate · Figure 3
PXRD (100) FWHM, Co-CuOAPc1.05 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Co-CuOAPc0.99 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Co-CuOAPc-3.89 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Co-CuOAPc-4.88 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Co-NiOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Co-NiOAPc454 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Co-NiOAPc8.4 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
Optical energy gap, Co-NiOAPc0.79 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Co-NiOAPc-3.91 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Co-NiOAPc-4.7 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Cu-CoOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Cu-CoOAPc183 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Cu-CoOAPc7.4 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD (100) FWHM, Cu-CoOAPc1.19 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Cu-CoOAPc0.91 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Cu-CoOAPc-4.05 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Cu-CoOAPc-4.96 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Cu-CuOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Cu-CuOAPc455 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Cu-CuOAPc9.7 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
Qualitative MOF formation completion time, Cu-CuOAPcMarked as a best value within this paper~5 min——Text
Approximate		9614 · Results / Qualitative Comparison of M1-CuOAPc Formation Rate · Figure 3
PXRD (100) FWHM, Cu-CuOAPc0.91 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Cu-CuOAPc0.79 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Cu-CuOAPc-4.16 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Cu-CuOAPc-4.95 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Cu-NiOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Cu-NiOAPc455 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Cu-NiOAPc9.1 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD (100) FWHM, Cu-NiOAPc0.97 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Cu-NiOAPcMarked as a best value within this paper0.69 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Cu-NiOAPc-4.25 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Cu-NiOAPc-4.94 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Ni-CoOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Ni-CoOAPc414 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Ni-CoOAPc7.9 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
Optical energy gap, Ni-CoOAPc0.87 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Ni-CoOAPc-3.91 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Ni-CoOAPc-4.78 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Ni-CuOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Ni-CuOAPc314 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Ni-CuOAPc11.2 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
Qualitative MOF formation completion time, Ni-CuOAPc~240 min——Text
Approximate		9614 · Results / Qualitative Comparison of M1-CuOAPc Formation Rate · Figure 3
PXRD (100) FWHM, Ni-CuOAPc0.79 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Ni-CuOAPc0.76 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Ni-CuOAPc-3.95 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Ni-CuOAPc-4.71 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5

Combined PXRD/FWHM crystallite-size analysis, N2 adsorption BET, UV-vis-NIR Tauc gap and PESA HOMO/LUMO summary

UV-visible and optical absorption spectroscopyX-ray diffraction and scatteringGas sorption and porosity

Ni-NiOAPc powder and cold-pressed pellet · Powder

Table S5 property summary for each pristine MOF

Geometry
powder or KBr pellet depending on method
Context
pristine framework powders
Measurement source
S31 · Additional figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area, Ni-NiOAPc412 m2/g——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD crystallite/coherence length, Ni-NiOAPcMarked as a best value within this paper12.3 nm——SI Table
Rounded Reported		S31 · Table S5 · Table S5
PXRD (100) FWHM, Ni-NiOAPc0.72 deg——Table
Exact Reported		9614 · Table 1 · Table 1
Optical energy gap, Ni-NiOAPc0.75 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
HOMO level, Ni-NiOAPc-3.93 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5
LUMO level, Ni-NiOAPc-4.68 eV——SI Table
Rounded Reported		S31 · Table S5 · Table S5