Electrical Transport — Effects of Transition Metals on Metal-Octaaminophthalocyanine-Based 2D Metal-Organic Frameworks

14 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Co-CoOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Co-CoOAPc pellet	8.9E-4 +/- 1.3E-4 mS/cm	8.9e-7 S/cm	+/- 1.3E-4 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Co-CuOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Co-CuOAPc pellet	0.20 +/- 0.027 mS/cm	0.0002 S/cm	+/- 0.027 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Co-NiOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Co-NiOAPc pellet	0.21 +/- 0.018 mS/cm	0.00021 S/cm	+/- 0.018 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Cu-CoOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Cu-CoOAPc pellet	0.35 +/- 0.035 mS/cm	0.00035 S/cm	+/- 0.035 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Cu-CuOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Cu-CuOAPc pellet	0.13 +/- 0.017 mS/cm	0.00013000000000000002 S/cm	+/- 0.017 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Cu-NiOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Cu-NiOAPc pellet	0.68 +/- 0.059 mS/cm	0.00068 S/cm	+/- 0.059 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Ni-CoOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Ni-CoOAPc pellet	0.10 +/- 0.012 mS/cm	0.0001 S/cm	+/- 0.012 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Ni-CuOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Ni-CuOAPc pellet	17.3 +/- 4.0 mS/cm	0.0173 S/cm	+/- 4.0 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Four-point-probe DC conductivity on cold-isostatically pressed pellets; Keithley 4200 SCS; CRX-6.5K probe station; sigma = (I/V) x ln(2)/(pi t)

Electrical conductivity

Ni-NiOAPc powder and cold-pressed pellet · Powder

Room-temperature pellet conductivity under vacuum (~1e-4 mbar); pellet pressed at 10 MPa for 30 s

Temperature: 298
Atmosphere: vacuum (~1e-4 mbar)
Geometry: cold-pressed pellet, linear four-contact probe, 0.5 mm contact spacing
Context: pristine framework pellet
Measurement source: 9619 · Methods / Conductivity Measurement · Figure 6; Figure 8; Figure S20; Table S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Room-temperature electrical conductivity, Ni-NiOAPc pelletMarked as a best value within this paper	54.3 +/- 4.8 mS/cm	0.0543 S/cm	+/- 4.8 mS/cm	SI Table Exact Reported	S31 · Table S5 · Table S5

Temperature-dependent four-point-probe conductivity; Arrhenius fit of ln(sigma/sigma_300K) vs 1000/T

Electrical conductivity

Co-CuOAPc powder and cold-pressed pellet · Powder

Thermally activated hopping fit over approximately 260-320 K from Figure S21-S25

Temperature: 260-320
Atmosphere: vacuum
Geometry: cold-pressed pellet, four-point probe
Context: pristine framework pellet
Measurement source: S22-S24 · Additional figures · Figures S21-S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy Ea, Co-CuOAPc	203 meV	—	—	Figure Axis Rounded Reported	S23 · Additional figures / Arrhenius fitting · Figure S24

Temperature-dependent four-point-probe conductivity; Arrhenius fit of ln(sigma/sigma_300K) vs 1000/T

Electrical conductivity

Cu-CoOAPc powder and cold-pressed pellet · Powder

Thermally activated hopping fit over approximately 260-320 K from Figure S21-S25

Temperature: 260-320
Atmosphere: vacuum
Geometry: cold-pressed pellet, four-point probe
Context: pristine framework pellet
Measurement source: S22-S24 · Additional figures · Figures S21-S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy Ea, Cu-CoOAPc	169 meV	—	—	Figure Axis Rounded Reported	S22 · Additional figures / Arrhenius fitting · Figure S21

Temperature-dependent four-point-probe conductivity; Arrhenius fit of ln(sigma/sigma_300K) vs 1000/T

Electrical conductivity

Cu-CuOAPc powder and cold-pressed pellet · Powder

Thermally activated hopping fit over approximately 260-320 K from Figure S21-S25

Temperature: 260-320
Atmosphere: vacuum
Geometry: cold-pressed pellet, four-point probe
Context: pristine framework pellet
Measurement source: S22-S24 · Additional figures · Figures S21-S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy Ea, Cu-CuOAPc	157 meV	—	—	Figure Axis Rounded Reported	S23 · Additional figures / Arrhenius fitting · Figure S23

Temperature-dependent four-point-probe conductivity; Arrhenius fit of ln(sigma/sigma_300K) vs 1000/T

Electrical conductivity

Cu-NiOAPc powder and cold-pressed pellet · Powder

Thermally activated hopping fit over approximately 260-320 K from Figure S21-S25

Temperature: 260-320
Atmosphere: vacuum
Geometry: cold-pressed pellet, four-point probe
Context: pristine framework pellet
Measurement source: S22-S24 · Additional figures · Figures S21-S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy Ea, Cu-NiOAPc	166 meV	—	—	Figure Axis Rounded Reported	S22 · Additional figures / Arrhenius fitting · Figure S22

Temperature-dependent four-point-probe conductivity; Arrhenius fit of ln(sigma/sigma_300K) vs 1000/T

Electrical conductivity

Ni-CuOAPc powder and cold-pressed pellet · Powder

Thermally activated hopping fit over approximately 260-320 K from Figure S21-S25

Temperature: 260-320
Atmosphere: vacuum
Geometry: cold-pressed pellet, four-point probe
Context: pristine framework pellet
Measurement source: S22-S24 · Additional figures · Figures S21-S25

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy Ea, Ni-CuOAPcMarked as a best value within this paper	74 meV	—	—	Figure Axis Rounded Reported	S24 · Additional figures / Arrhenius fitting · Figure S25