Spectroscopy — Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport

Measurement evidence

Spectroscopy

Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport · Wang Z., Walter L.S., Wang M. et al. · Journal of the American Chemical Society · 2021 · 13624-13632

1 measurement group · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

ATR-FTIR, Raman, XPS, SEM-EDX, XANES, EXAFS, UV-vis

Infrared spectroscopy Raman spectroscopy X-ray photoelectron spectroscopy UV-visible and optical absorption spectroscopy X-ray absorption spectroscopy Scanning electron microscopy Elemental microanalysis and mapping

Cu2[PcCu-O8] edge-on MOF film · Thin Film

FTIR on copper foil; XPS AXIS Ultra DLD calibrated to C1s 284.6 eV; UV-vis on 3 x 3 cm quartz wafer

Temperature: room temperature for UV-vis
Context: Pristine Cu2[PcCu-O8] film
Measurement source: p. 4 · Crystallinity and Molecular Orientation · Figures S5-S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu:O ratio by SEM-EDX	Cu:O = 1:2.5	—	—	Text Exact Reported	p. 4 · Crystallinity and Molecular Orientation · Figure S7
EXAFS Cu-O peak	about 1.52 A	—	—	Text Approximate	p. 4 · Crystallinity and Molecular Orientation · Figure S8b
OH mode disappearance by ATR-FTIR	OH modes around 3200 cm^-1 vanish	—	—	Text Qualitative	p. 4 · Crystallinity and Molecular Orientation · Figure S5a
Optical band gap by UV-vis/Tauc	about 1.17 eV	—	—	Text Approximate	SI p. 22 · Supporting Figures and Tables · Figure S9
Cu:O ratio by XPS	Cu:O = 1:2.6	—	—	Text Exact Reported	p. 4 · Crystallinity and Molecular Orientation · Figure S6