Other — Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport

Measurement evidence

Other

Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal-Organic Framework Films toward Directional Charge Transport · Wang Z., Walter L.S., Wang M. et al. · Journal of the American Chemical Society · 2021 · 13624-13632

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Langmuir-Blodgett surface pressure-mean molecular area (pi-A) isotherm

PcCu-OH8 self-assembly on water · Thin Film

50 ul freshly prepared PcCu-OH8 (0.47 mM) in chloroform/DMF (2:1) spread on water; 10 min evaporation; Delrin barriers at 5 mm min^-1 to 30 mN m^-1

Atmosphere: Ambient
Geometry: Air/water interface
Context: Precursor ligand orientation control
Measurement source: SI p. 14 · Supporting Figures and Tables · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PcCu-OH8 sharp pressure rise molecular area	about 36 A^2	—	—	Text Approximate	p. 3 · Design, Synthesis, and Characterization · Figure S1
Theoretical cross-section area per PcCu-OH8	35.7 A^2	—	—	Text Exact Reported	p. 3 · Design, Synthesis, and Characterization · Figure S1
PcCu-OH8 molecule density in self-assembly beaker	about 3.4 x 10^-6 mmol cm^-2	—	—	Text Approximate	p. 3 · Design, Synthesis, and Characterization

Langmuir-Blodgett pi-A isotherm

PcFe-OH8 Langmuir film on water · Thin Film

50 ul PcFe-OH8 (0.45 mM) in chloroform/DMF (2:1) spread on water; 10 min evaporation; compressed at 5 mm min^-1 to 22 mN m^-1

Atmosphere: Ambient
Geometry: Air/water interface
Context: Precursor ligand orientation control
Measurement source: SI p. 26 · Supporting Figures and Tables · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PcFe-OH8 isotherm final surface pressure	22 mN m^-1	—	—	Caption Exact Reported	SI p. 26 · Supporting Figures and Tables · Figure S13