Spectroscopy — Large Single Crystals of Two-Dimensional π-Conjugated Metal-Organic Frameworks via Biphasic Solution-Solid Growth

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Evaporated HHTP thin film on silicon · Thin Film

Evaporated HHTP film on silicon; ordinary and extraordinary refractive indices fitted.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP ellipsometry film thickness	34 nm	—	—	Caption Exact Reported	S6 · Figure caption · Figure S1
HHTP film molecular orientation order parameter	-0.22	—	—	Text Exact Reported	p002 · Results and Discussion · Figure S1
Reference order parameter for perfect horizontal alignment	-0.5	—	—	Text Exact Reported	p002 · Results and Discussion
Reference order parameter for random orientation	0	—	—	Text Exact Reported	p002 · Results and Discussion

Ni-CAT-1 powder · Powder

MOF powder diluted 1% in KBr for diffuse reflectance; dispersed in methanol and drop-cast on quartz for transmission.

Temperature: room temperature
Atmosphere: Not specified
Geometry: Powder optical spectroscopy
Context: pristine Ni-CAT-1 powder
Measurement source: S3 and S18 · Optical band gap measurement; Figure caption · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Rounded small band gap used in transport discussion	0.2 eV	—	—	Text Rounded Reported	p005 · Results and Discussion · Figure S13
Optical band gap from Tauc plot	0.18 eV	—	—	Text Exact Reported	S3 · Optical band gap measurement · Figure S13B