Diffraction Structure — Large Single Crystals of Two-Dimensional π-Conjugated Metal-Organic Frameworks via Biphasic Solution-Solid Growth

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solution-solid-grown Co-CAT-1 single crystal · Single Crystal

Single Co-CAT-1 crystal grown by solution-solid route; EDS mapping and FTIR spectrum compared with powder.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co atomic percentage in Co-CAT-1 crystal EDS table	Co atomic % 4.14	—	—	Visual Estimate Approximate	S22 · Rendered figure table · Figure S17C
Co-CAT-1 single-crystal/powder FTIR match	vibrational features of the crystal and powder are similar	—	—	Caption Qualitative	S23 · Figure caption · Figure S18

Ni-CAT-1 powder · Powder

PXRD of hydrothermally synthesized Ni-CAT-1 powder compared with simulated Co-CAT-1 and Cu-CAT-1 patterns.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni-CAT-1 powder PXRD match	major peaks match well with simulated Co-CAT-1	—	—	Caption Qualitative	S14 · Figure caption · Figure S9

Solution-solid-grown Ni-CAT-1 single-crystal plates on Si/SiO2 · Single Crystal

Low- and high-resolution TEM, Fourier transform, elemental mapping and IR comparison with powder.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EDS Ni:C ratio	Ni:C ratio of 1:12	—	—	Text Exact Reported	p004 · Results and Discussion · Figure 3C; Figure S10
FTIR match between single crystal and powder	vibrational bands overlap	—	—	Text Qualitative	p004 · Results and Discussion · Figure 3D
TEM structure observation	uniform hexagonal structure	—	—	Text Qualitative	p004 · Results and Discussion · Figure 3A-B
TEM/FFT lattice spacing	2.1 nm	—	—	Caption Exact Reported	p003 · Figure caption · Figure 3A