Spectroscopy — Solvent-Directed Assembly of π-Stacked 3D Metal-Organic Frameworks with Tunable Conductivity Enhanced by C60 Encapsulation

3 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NU-4003 · Single Crystal

D2SO4 digestion, DMSO-d6 solvent, mesitylene internal standard; estimates missing-linker defects for NU-4000-NU-4003

Measurement source: SI p005-p006 / S5-S6 · Defect Quantification by Solution NMR · Figures S38-S41

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
estimated linker incorporation deviation / missing-linker defect indicator	approximately 11%	—	—	Text Approximate	main p005 / journal p20903 · Electrical Conductivity · Figures S38-S41
estimated linker incorporation deviation / missing-linker defect indicator	approximately 4%	—	—	Text Approximate	main p005 / journal p20903 · Electrical Conductivity · Figures S38-S41
estimated linker incorporation deviation / missing-linker defect indicator	approximately -12%	—	—	Text Approximate	main p005 / journal p20903 · Electrical Conductivity · Figures S38-S41
estimated linker incorporation deviation / missing-linker defect indicator	approximately 24%	—	—	Text Approximate	main p005 / journal p20903 · Electrical Conductivity · Figures S38-S41

NU-4003-C60 · Single Crystal

785 nm excitation; comparison of C60, NU-4003, and NU-4003-C60

Measurement source: main p006 / journal p20904 · Electrical Conductivity · Figure S24

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman C60 Ag(1) mode	509 cm^-1	—	—	Text Rounded Reported	main p006-p007 / journal p20904-p20905 · Electrical Conductivity · Figure 3c; Figure S24

NU-4003 · Single Crystal

Kubelka-Munk-transformed diffuse reflectance spectra for NU-4003 and C60-loaded variants

Measurement source: main p007 / journal p20905 · Electrical Conductivity · Figure 4b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap Eg	3.11 eV	—	—	Text Rounded Reported	main p007 / journal p20905 · Electrical Conductivity · Figure 4b
optical band gap Eg	2.99 eV	—	—	Text Rounded Reported	main p007 / journal p20905 · Electrical Conductivity · Figure 4b
optical band gap Eg	2.96 eV	—	—	Text Rounded Reported	main p007 / journal p20905 · Electrical Conductivity · Figure 4b
optical band gap Eg	2.90 eV	—	—	Text Rounded Reported	main p007 / journal p20905 · Electrical Conductivity · Figure 4b
optical band gap Eg	2.88 eV	—	—	Text Rounded Reported	main p007 / journal p20905 · Electrical Conductivity · Figure 4b
charge-transfer absorption band	380-600 nm	—	—	Text Range	main p006-p007 / journal p20904-p20905 · Electrical Conductivity · Figure 3c; Figure S24